스테아린산 알루미늄

Cosmetic ingredients (Aluminum Stearate) -> CIR (Cosmetic Ingredient Review)

Cosmetic ingredients (Aluminum Tristearate) -> CIR (Cosmetic Ingredient Review)

Emulsion stabilizing; Viscosity controlling; Emollient; Opacifying

White powder

Hard material

Insoluble in water; soluble in ethanol, petroleum ether.

When freshly made, soluble in alcohol, benzene, oil turpentine, mineral oils.

Insoluble in alcohol, ether; soluble in alkali

CBI; Dry Powder

White solid; [Hawley] White powder; Insoluble in water; [MSDSonline]

Low melting solids or colorless, volatile liquids. /Alkylaluminum halides/

Less sensitive than trialkylaminums to oxidation upon exposure to air. /Alkylaluminum halides/

This chemical does not meet GHS hazard criteria for 99.6% (445 of 447) of all reports.

Not Classified

Aggregated GHS information provided per 447 reports by companies from 2 notifications to the ECHA C&L Inventory.

Chemical: Octadecanoic acid, aluminium salt

Octadecanoic acid, aluminum salt (3:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Octadecanoic acid, aluminum salt (3:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 23-12-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/19014

Octadecanoic acid, aluminium salt: Does not have an individual approval but may be used under an appropriate group standard

Certain polymerization catalysts, such as aluminum alkyls, react & burn violently on contact with water. /Aluminum alkyls/

Aluminum alkyls are organic aluminum compounds that are highly reactive and dangerous because of spontaneous burning in air. /Aluminum alkyls/

Prophoric material in flammable solvent. Vapors are heavier than air & may travel to a source of ignition & flash back. /Aluminum alkyls/

Substances classified as stabilizers, when migrating from food-packaging material shall incl: Aluminum tristearate.

Fatty acids derived from animal or vegetable fats and oils; and salts or such acids, single or mixed are indirect food additives for use only as a component of adhesives. /Fatty acid aluminum salts/

Cosmetic, Toiletry and Fragrance Assoc; J Am Coll Toxicol 1 (2): 143-77 (1982). A review with 89 references on the chemical and physical properties, biological and toxicological properties of lithium stearate, aluminum distearate, aluminum stearate, aluminum tristearate, ammonium stearate, calcium stearate, magnesium stearate, potassium stearate, sodium stearate, and zinc stearate.

Inert ingredients used pre- and post-harvest; exemptions from the requirement of a tolerance. Residues of the following materials are exempted from the requirement of a tolerance when used in accordance with good agricultural practice as inert (or occasionally active) ingredients in pesticide formulations applied to growing crops or to raw agricultural commodities after harvest. Aluminum tristearate as a surfactant is included on this list.

/GUIDE 135: SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE/ Fire or Explosion: Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated. /Aluminum alkyls/

/GUIDE 135: SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE/ Health: Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution. /Aluminum alkyls/

/GUIDE 135: SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Stay upwind. Keep unauthorized personnel away. Keep out of low areas. /Aluminum alkyls/

/GUIDE 135: SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing will only provide limited protection. /Aluminum alkyls/

For more DOT Emergency Guidelines (Complete) data for ALUMINUM TRISTEARATE (8 total), please visit the HSDB record page.

Recommended Exposure Limit: 10-Hr Time-Weighted Avg: 10 mg/cu m (total). /Aluminum/

Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 5 mg/cu m (resp). /Aluminum/

Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 2 mg/cu m. /Aluminum (soluble salts and alkyls, as Al)/

Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 5 mg/cu m. /Aluminum (pyro powders and welding fumes, as Al)/

(AZ) ARIZONA 73 ug/l /Aluminum/

(CA) CALIFORNIA 200 ug/l /Aluminum/

(ME) MAINE 1430 ug/l /Aluminum/

The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article.

The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials.

No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./

Stop flow of liquid before extinguishing fire. Use dry chemical or carbon dioxide. DO NOT use water as straight stream directly on spilled material. Water fog can be used to control fire. DO NOT use halogenated extinguishing agents on spilled material. Violent reaction may result. Use water spray to keep fire-exposed containers cool. Fight fire from protected location or maximum possible distance. /Aluminum Alkyls/

Extremely reactive with air, moisture and compounds containing active hydrogen and therefore must be kept under a blanket of inert gas. /Aluminum alkyls/

In general, materials ... toxic as stored or which can decompose into toxic components ... Should be stored in cool ... ventilated place, out of ... sun, away from ... fire hazard ... be periodically inspected and monitored. Incompatible materials should be isolated ...

All possibility of contact with water must be avoided. Solution containing not more than 20% of these compounds in non-reactive solvents, however, can be handled without risk of spontaneous ignition. /Aluminum alkyls/

Must be stored in an inert atmosphere; sensitive to oxidation and hydrolysis in air. /Trialkylaluminums/

Separate from air, water, halocarbons, alcohols. Store in a cool, dry, well-ventilated location. Outside or detached storage is preferred. Inside storage should be in a standard flammable liquid storage warehouse, room, or cabinet. /Aluminum alkyls/

Aluminum compounds are treated under anhydrous conditions to prevent violent reactions, recover solvent, and form Al compounds suitable for landfill by reaction with anhydrous hydrolysis agent, eg calcium hydroxide. /Aluminum compounds/

SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations.

SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

Work clothing that becomes wet or significantly contaminated should be removed and replaced. /Aluminum (soluble salts and alkyls, as Al)/

Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises. /Aluminum (soluble salts and alkyls, as Al)/

The worker should immediately wash the skin when it becomes contaminated. /Aluminum (soluble salts and alkyls, as Al)/

SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers. Contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.

Inert ingredients used pre- and post-harvest; exemptions from the requirement of a tolerance. Residues of the following materials are exempted from the requirement of a tolerance when used in accordance with good agricultural practice as inert (or occasionally active) ingredients in pesticide formulations applied to growing crops or to raw agricultural commodities after harvest. Aluminum tristearate as a surfactant is included on this list.

1.0 [mg/m3], respirable fraction

8 hr Time Weighted Avg (TWA): 1 mg/cu m (respirable fraction). /Aluminum metal and insoluble compounds/

A4; Not classifiable as a human carcinogen. /Aluminum metal and insoluble compounds/

Excursion Limit Recommendation: Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than a total of 30 minutes during a work day, and under no circumstances should they exceed 5 times the TLV-TWA, provided that the TLV-TWA is not exceeded. /Aluminum metal and insoluble compounds/

Wear appropriate personal protective clothing to prevent skin contact. /Aluminum (soluble salts and alkyls, as Al/

Wear appropriate eye protection to prevent eye contact. /Aluminum (soluble salts and alkyls, as Al)/

Protective clothing and a high standard of training in the necessary precautionary measures are essential for the handling of the materials. /Aluminum alkyls/

Aluminum targets the nervous system and causes decreased nervous system performance and is associated with altered function of the blood-brain barrier. The accumulation of aluminum in the body may cause bone or brain diseases. High levels of aluminum have been linked to Alzheimer's disease. A small percentage of people are allergic to aluminium and experience contact dermatitis, digestive disorders, vomiting or other symptoms upon contact or ingestion of products containing aluminium. (L739, L740)

The CIR Expert Panel concluded that the following ingredients are safe in the present practices of use and concentration described in the safety assessment when formulated to be non-irritating and non-sensitizing, which may be based on a QRA...Aluminum Stearate...

Safe for use in cosmetics, with qualifications

The CIR Expert Panel concluded that the following ingredients are safe in the present practices of use and concentration described in the safety assessment when formulated to be non-irritating and non-sensitizing, which may be based on a QRA...Aluminum Tristearate...

Safe for use in cosmetics, with qualifications

The main target organs of aluminum are the central nervous system and bone. Aluminum binds with dietary phosphorus and impairs gastrointestinal absorption of phosphorus. The decreased phosphate body burden results in osteomalacia (softening of the bones due to defective bone mineralization) and rickets. Aluminum's neurotoxicity is believed to involve several mechanisms. Changes in cytoskeletal protein functions as a results of altered phosphorylation, proteolysis, transport, and synthesis are believed to be one cause. Aluminum may induce neurobehavioral effects by affecting permeability of the blood-brain barrier, cholinergic activity, signal transduction pathways, lipid peroxidation, and impair neuronal glutamate nitric oxide-cyclic GMP pathway, as well as interfere with metabolism of essential trace elements because of similar coordination chemistries and consequent competitive interactions. It has been suggested that aluminum's interaction with estrogen receptors increases the expression of estrogen-related genes and thereby contributes to the progression of breast cancer (A235), but studies have not been able to establish a clear link between aluminum and increased risk of breast cancer (A15468). Certain aluminum salts induce immune responses by activating inflammasomes. (L739, A235, A236)

Inhalating aluminum dust causes coughing and abnormal chest X-rays. A small percentage of people are allergic to aluminium and experience contact dermatitis, digestive disorders, vomiting or other symptoms upon contact or ingestion of products containing aluminium. (L739, L740)

/CASE REPORTS/ Pulmonary aluminosis first seen in Germany between 1938 and 1945... reappeared in United Kingdom between 1952 and 1959. All cases were associated with exposure to a submicron-sized aluminum polytechnic flake which was lubricated with stearic acid, which forms aluminum stearate to retard surface oxidation during milling of such flake. This lubricant could easily be washed off. In intracellular milieu, removal of such surface oil permits exposure of oxygen to aluminum; this results in exothermic reaction and potential for tissue damage. It appears that cases occured only where this oily lubricant was used to manufacture near submicron-sized pyrotechnic flake but never where similar flake has been manufactured using polar lubricants.

Not listed by IARC. IARC classified aluminum production as carcinogenic to humans (Group 1), but did not implicate aluminum itself as a human carcinogen. (L135) A link between use of aluminum-containing antiperspirants and increased risk of breast cancer has been proposed (A235), but studies have not been able to establish a clear link (A15468).

Substances classified as stabilizers, when migrating from food-packaging material shall incl: Aluminum tristearate.

Fatty acids derived from animal or vegetable fats and oils; and salts or such acids, single or mixed are indirect food additives for use only as a component of adhesives. /Fatty acid aluminum salts/

Inert ingredients used pre- and post-harvest; exemptions from the requirement of a tolerance. Residues of the following materials are exempted from the requirement of a tolerance when used in accordance with good agricultural practice as inert (or occasionally active) ingredients in pesticide formulations applied to growing crops or to raw agricultural commodities after harvest. Aluminum tristearate as a surfactant is included on this list.

(AZ) ARIZONA 73 ug/l /Aluminum/

(CA) CALIFORNIA 200 ug/l /Aluminum/

(ME) MAINE 1430 ug/l /Aluminum/

Aluminum is poorly absorbed following either oral or inhalation exposure and is essentially not absorbed dermally. The bioavailability of aluminum is strongly influenced by the aluminum compound and the presence of dietary constituents which can complex with aluminum and enhance or inhibit its absorption. Aluminum binds to various ligands in the blood and distributes to every organ, with highest concentrations found in bone and lung tissues. In living organisms, aluminum is believed to exist in four different forms: as free ions, as low-molecular-weight complexes, as physically bound macromolecular complexes, and as covalently bound macromolecular complexes. Absorbed aluminum is excreted principally in the urine and, to a lesser extent, in the bile, while unabsorbed aluminum is excreted in the faeces. (L739)

CIR ingredient: Aluminum Stearate

CIR ingredient: Aluminum Tristearate

Used for waterproofing fabrics and ropes; in paint and varnish driers; for thickening lubricating oils; in cements (waterproofing additive); in light-sensitive photographic compositions; as gelling agent for alkyd paints and varnishes; as defoamer for oil drilling fluids; as retarder for polysulfide dental impression materials; in greases, lubricants, cutting compounds, cosmetics, and pharmaceuticals; as flatting agent; as defoaming agent in beet sugar and yeast processing; as a water-repellent soap (for natural stone surfaces); to gel petroleum fractions in the preparation of high-energy rocket fuels and plastic explosives; in pesticide formulations; [HSDB]

Metal Machining [Category: Heat or Machine]

Waterproofing fabrics, ropes; in paint and varnish driers; thickening lubricating oils; in cements; in light-sensitive photographic compositions

Gelling agent for alkyd paints and varnishes

2023: 100,000 - <250,000 lb

(1979) 9.26X10+8 G (MONO & TRISTEARATE MIXT)

(1981) 3.67X10+8 G (MONO & TRISTEARATE MIXT)

High quality aluminum tristearate is made by reaction of aluminum isopropoxide and stearic acid in anhydrous pyridine; the product precipitates as a pyridine complex. Infrared analysis indicates that no hydroxyl remains after the pyridine is removed under vacuum.

Reaction of aluminum isopropoxide with stearic acid in anhydrous pyridine or benzene

Food Additives -> ANTICAKING_AGENT; EMULSIFIER -> JECFA Functional Classes

Cosmetics -> Emulsion stabilizing; Viscosity controlling; Emollient; Opacifying

Plastics Material and Resin Manufacturing

Octadecanoic acid, aluminum salt (3:1): ACTIVE