Aluminum Stearate → Ethylene brassylate

HRID 615482

반응식

HRID 615482 반응식
[C:1]([O-:17])(=[O:16])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13]([O-:15])=[O:14].[Na+].[Na+].[C:20]([O-])(=O)[CH2:21]CCCCCCCCCCCCCCCC.[Al+3].C([O-])(=O)CCCCCCCCCCCCCCCCC.C([O-])(=O)CCCCCCCCCCCCCCCCC.[Na].[Al]>>[C:1]1(=[O:17])[O:16][CH2:21][CH2:20][O:15][C:13](=[O:14])[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

참가 물질

5

반응물 4

HCID 12496Aluminum StearateHCID 5359268AluminumHCID 5360545SodiumHCID 11514768Sodium brassylate

생성물 1

HCID 61014Ethylene brassylate수율 88.1%

반응 조건

온도
200 °C

실험 절차

Sodium brassylate (0.33 gram) and aluminum stearate (1.09 gram) were added to 70 grams poly(ethylene brassylate) and the mixture heated at 200° C. until a homogeneous viscous mass was obtained. The molar ratio of sodium to aluminum was 2:1. The temperature was then increased to 312° C. and the pressure reduced to 0.3-0.5 mm Hg. The depolymerization reaction was complete in about 3 hours and 88.1 percent yield ethylene brassylate was obtained.

후처리

  1. customwas obtained
  2. temperatureThe temperature was then increased to 312° C.
  3. customThe depolymerization reaction

출처 및 근거

ORD 기록
ord-f2e2506a754142c8ad95ccf6b62fcee5
출처 데이터셋
uspto-grants-1985_02
특허 번호
US04499288

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