Chlorodiisopropylphosphine

HCID 538967

기본 정보

CAS
40244-90-4
표준 SMILES
CC(C)P(Cl)C(C)C
InChIKey
JZPDBTOWHLZQFC-UHFFFAOYSA-N
분자식
C6H14ClP
평균 분자량
152.6 g/mol
단동위원소 질량
152.0521651

이름 및 식별자

우선 이름
Chlorodiisopropylphosphine
IUPAC
chloro-di(propan-2-yl)phosphane
영어명
Chlorodiisopropylphosphine
분자식
C6H14ClP
분자량
152.6

이름 및 동의어

Chlorodiisopropylphosphine40244-90-45FG5N54CYBDTXSID10337132RefChem:575823DTXCID00288220629-426-0DiisopropylchlorophosphinePhosphinous chloride, bis(1-methylethyl)-chloro-di(propan-2-yl)phosphaneChlorobis(isopropyl)phosphineiPr2PCl
이름 더 보기
Di-i-propyLAURORA KA-131898% (i-Pr)2PClCHLORODIISOPROPYLPHOSHINEbis-isopropylchlorophosphineCHLORODIISOPROPYLPHOSPHINE,96%
MFCD00015027ChlorodiiosopropylphosphineUNII-5FG5N54CYBP,P-Bis(1-methylethyl)phosphinous chloridePhosphinous chloride, P,P-bis(1-methylethyl)-Di-i-propylchlorophosphinedi-isopropylchlorophosphineC6H14ClP

데이터베이스 식별자

CAS
40244-90-4
PubChem CID
538967
DTXSID
DTXSID10337132
UNII
5FG5N54CYB
EC Number
629-426-0
Nikkaji
J121.063G

물성

구조 계산 물성

XLogP
2.3
극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
2
무거운 원자 수
8

물리화학적 성질

끓는 점
69 °C33 · 69 °C33 mm Hg(lit.)
밀도
0.959 g/mL · 0.959 g/mL at 25 °C(lit.)
굴절률
20 · n20/D 1.475(lit.)
인화점
39 °F · 39 °F
저장 조건
Refrigerator
물리적 상태
액체

화학적 성질

Colorless to light yellow liqui

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids];H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 42 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Hazard Classes and CategoriesFlam. Liq. 2 (100%);Skin Corr. 1B (100%)

안전 데이터

wgk
3
ridadr
UN 2924 3/PG 2
HS 번호
29310099
risk_code
11-34
hazard_code
F,C
safety_code
16-26-27-36/37/39-45-1

화학 및 산업

응용 분야 · 2건

개요Chlorodiisopropylphosphine is an organophosphorus compound of particular interest in synthetic chemistry, where it is used as a reagent in the preparation of phosphine ligands for transition metal complexes. Its utility in synthesising these complexes is due to the reactivity of the chloro group, which other groups can substitute to create a diverse array of ligands. This reactivity is also exploited in the study of catalysis, as the resulting phosphine ligands can be used to modulate the activity and selectivity of metal catalysts. In addition, Chlorodiisopropylphosphine is investigated for its potential in forming new organophosphorus compounds with applications in materials science. Researchers are also interested in the compound′s role in synthesising flame retardants, where its phosphorus content could contribute to the material′s flame-retarding properties.

용도Chlorodiisopropylphosphine can be used: To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.

공급사100 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
阿诺西(上海)生物技术有限公司400-1107768 15058188853 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
杭州鸿喜生物医药科技有限公司18989489206 · [email protected]
武汉欣扬瑞和化学科技有限公司13720274133 · [email protected]

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26건

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