기본 정보
- CAS
40244-90-4- 표준 SMILES
CC(C)P(Cl)C(C)C- InChIKey
JZPDBTOWHLZQFC-UHFFFAOYSA-N- 분자식
- C6H14ClP
- 평균 분자량
- 152.6 g/mol
- 단동위원소 질량
- 152.0521651
이름 및 식별자
- 우선 이름
- Chlorodiisopropylphosphine
- IUPAC
- chloro-di(propan-2-yl)phosphane
- 영어명
- Chlorodiisopropylphosphine
- 분자식
- C6H14ClP
- 분자량
- 152.6
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
40244-90-4- PubChem CID
- 538967
- DTXSID
DTXSID10337132- UNII
- 5FG5N54CYB
- EC Number
- 629-426-0
- Nikkaji
- J121.063G
물성
구조 계산 물성
- XLogP
- 2.3
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 0
- 회전 가능 결합 수
- 2
- 무거운 원자 수
- 8
- 형식 전하
- 0
- 복잡도
- 53
물리화학적 성질
- 끓는 점
- 69 °C33 · 69 °C33 mm Hg(lit.)
- 밀도
- 0.959 g/mL · 0.959 g/mL at 25 °C(lit.)
- 굴절률
- 20 · n20/D 1.475(lit.)
- 인화점
- 39 °F · 39 °F
- 저장 조건
- Refrigerator
- 물리적 상태
- 액체
- 색상
- 맑은 연한 노란색
- InChI
- InChI=1S/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3
- InChIKey
- JZPDBTOWHLZQFC-UHFFFAOYSA-N
- SMILES
- P(C(C)C)(C(C)C)Cl
화학적 성질
Colorless to light yellow liqui
안전 및 규제
GHS 분류
GHS Classification
Danger
H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids];H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 42 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
유해성 정보
안전 데이터
- wgk
- 3
- ridadr
- UN 2924 3/PG 2
- HS 번호
- 29310099
- risk_code
- 11-34
- hazard_code
- F,C
- safety_code
- 16-26-27-36/37/39-45-1
- 포장분류
- II
- 위험 등급
- 3.1
- Hazard Classifications
- Flam. Liq. 2Skin Corr. 1B
- 스토리지 클래스
- 3 - Flammable liquids
화학 및 산업
응용 분야
개요Chlorodiisopropylphosphine is an organophosphorus compound of particular interest in synthetic chemistry, where it is used as a reagent in the preparation of phosphine ligands for transition metal complexes. Its utility in synthesising these complexes is due to the reactivity of the chloro group, which other groups can substitute to create a diverse array of ligands. This reactivity is also exploited in the study of catalysis, as the resulting phosphine ligands can be used to modulate the activity and selectivity of metal catalysts. In addition, Chlorodiisopropylphosphine is investigated for its potential in forming new organophosphorus compounds with applications in materials science. Researchers are also interested in the compound′s role in synthesising flame retardants, where its phosphorus content could contribute to the material′s flame-retarding properties.
용도Chlorodiisopropylphosphine can be used: To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.
상·하류 제품 정보
하류 제품
공급사100 곳
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