Bis(eta-cyclopentadienyl) iron → Bis(eta-cyclopentadienyl) iron

HRID 249569

반응식

HRID 249569 반응식
Cl[Sn]Cl.[Cl:4][CH2:5][CH2:6][CH2:7][C:8]([C-:10]1[CH:14]=[CH:13][CH:12]=[CH:11]1)=[O:9].[CH-:15]1[CH:19]=[CH:18][CH:17]=[CH:16]1.[Fe+2:20].[CH-:21]1[CH:25]=[CH:24][CH:23]=[CH:22]1.[CH-:26]1[CH:30]=[CH:29][CH:28]=[CH:27]1.[Fe+2].[Cl:32][CH2:33][CH2:34][CH2:35][C:36]([C-]1C=CC=C1)=[O:37].[C-]1(C(=O)CCC[Cl:52])C=CC=C1.[Fe+2]>C(Cl)Cl.[Al+3].[Cl-].[Cl-].[Cl-].O=[Pt]=O.C(O)(=O)C>[Cl:4][CH2:5][CH2:6][CH2:7][C:8]([C-:10]1[CH:14]=[CH:13][CH:12]=[CH:11]1)=[O:9].[CH-:15]1[CH:19]=[CH:18][CH:17]=[CH:16]1.[Fe+2:20].[CH-:21]1[CH:25]=[CH:24][CH:23]=[CH:22]1.[CH-:26]1[CH:30]=[CH:29][CH:28]=[CH:27]1.[Fe+2:20].[Cl:32][CH2:33][CH2:34][CH2:35][C:36]([Cl:52])=[O:37]

참가 물질

11

반응물 4

HCID 7611Bis(eta-cyclopentadienyl) ironHCID 24479Stannous ChlorideHCID 178520619HCID 178520619, 화합물HCID 178520620HCID 178520620, 화합물

생성물 3

HCID 7611Bis(eta-cyclopentadienyl) ironHCID 783704-Chlorobutyryl chlorideHCID 178520619HCID 178520619, 화합물

시약·촉매·용매 4

HCID 345198Adams' catalyst촉매HCID 6451240Aluminum(III) Chloride촉매HCID 176Acetic Acid용매HCID 6344Dichloromethane용매

실험 절차

In an inert atmosphere, 170 mg of PtO2.xH2O (containing 80% of Pt) and 5 mg of anhydrous SnCl2 are introduced into the glass beaker. 120 cm3 of glacial acetic acid and 29.1 g (0.10 mol) of 4-chlorobutyroylferrocene whose main impurities are 1.4% by weight of ferrocene and 0.88% by weight of 1,1'-di(4-chlorobutyroyl)ferrocene are then poured in. This 4-chlorobutyroylferrocene was obtained in the customary manner by a reaction of the Friedel-Crafts type between ferrocene and 4-chlorobutyryl chloride in CH2Cl2 in the presence of AlCl3 as catalyst, followed by recrystallisation of the crude product obtained from hexane.

후처리

  1. additionare introduced into the glass beaker
  2. additionare then poured in

출처 및 근거

ORD 기록
ord-7535c6cada5e4d8aa4c298bdb54a4fc2
출처 데이터셋
uspto-grants-1993_05
특허 번호
US05214175

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