Benzoyl chloride, 3-nitro-

HCID 8495CAS 121-90-4

기본 정보

표준 SMILES
O=C(Cl)c1cccc([N+](=O)[O-])c1
InChIKey
NXTNASSYJUXJDV-UHFFFAOYSA-N
분자식
C7H4ClNO3
평균 분자량
185.56 g/mol
단동위원소 질량
184.98797067

개요

M-nitrobenzoyl chloride is a yellow to brown liquid. Unstable at room temperatures; requires refrigeration when not in use.

이름 및 식별자

우선 이름
Benzoyl chloride, 3-nitro-
IUPAC
3-nitrobenzoyl chloride
영어명
m-Nitrobenzoyl chloride
분자식
C7H4ClNO3
분자량
185.56

이름 및 동의어

3-Nitrobenzoyl chloride121-90-4M-NITROBENZOYL CHLORIDEBenzoyl chloride, 3-nitro-CCRIS 1186Chlorid kyseliny m-nitrobenzooveDTXSID9025740NSC 5380EINECS 204-505-9BRN 0777186Chlorid kyseliny m-nitrobenzoove [Czech]AI3-14869
이름 더 보기
m-Nitrobenzoyl chlorLABOTEST-BB LTBB000612m-Nitrobenzoylchroride3-nitro-benzoylchloridm-nitro-benzoylchlorid1 m-Nitrobenzoyl ChloroBenzoylchloride,3-nitro-3-NitrobenzoylChloride>
3-NITROBENZOIC ACID CHLORIDEDTXCID105740meta-nitrobenzoyl chlorideRefChem:5664573-NITROBENZOIC ACID, CHLORIDE204-505-9Benzoyl chloride, m-nitro-3-Nitro-benzoyl chloride

데이터베이스 식별자

CAS
121-90-4
PubChem CID
8495
DTXSID
DTXSID9025740
ChEMBL
CHEMBL1517721
UNII
QAX5Y35ZPW
EC Number
204-505-9
Nikkaji
J36.096A

물성

구조 계산 물성

XLogP
2.8
극성 표면적
62.9 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
3
회전 가능 결합 수
1
무거운 원자 수
12

실험 및 물리화학적 성질

SpringerMaterials PropertiesBoiling point
SolubilityDecomposes (NTP, 1992)
Flash Pointgreater than 233.6 °F (NTP, 1992)
Boiling Point527 to 532 °F at 760 mmHg (NTP, 1992)
Melting Point95 °F (NTP, 1992)
Vapor Density6.43 (NTP, 1992) - Heavier than air; will sink (Relative to Air)

물리화학적 성질

녹는점
31 · 31-34 °C(lit.)
끓는 점
275 · 275-278 °C(lit.)
밀도
1.42 · 1.42
굴절률
1.581 · 1.5810 (estimate)
인화점
230 °F · >230 °F
용해도
soluble in Ether,Benzene,Toluene

화학적 성질

BROWN LOW MELTING SOLID

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H311 (89.1%): Toxic in contact with skin [Danger Acute toxicity, dermal]

P260, P262, P264, P264+P265, P270, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P361+P364, P362+P364, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

DOT LabelCorrosive
Fire HazardsThis chemical is combustible. (NTP, 1992)
Health Hazards · 1건

ACUTE/CHRONIC HAZARDS: This chemical is unstable at room temperature or when exposed to sources of ignition. When heated to decomposition it emits highly toxic fumes. It will react with water or steam to produce toxic and corrosive fumes. (NTP, 1992)

Reactive GroupNitro, Nitroso, Nitrate, and Nitrite Compounds, Organic
Reactivity AlertsWater-Reactive
Reactivity Profile · 1건

M-NITROBENZOYL CHLORIDE is incompatible with bases (including amines), with strong oxidizing agents, and with alcohols. May react with reducing agents. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

안전 및 보호

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Personal Protective Equipment (PPE)MINIMUM PROTECTIVE CLOTHING: If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves.

안전 데이터

wgk
3
tsca
TSCA listed
rtecs
DM6646000
ridadr
UN 2923 8/PG 3
HS 번호
29163900
risk_code
5-21-34-37

화학 및 산업

용도 및 제조

General Manufacturing InformationBenzoyl chloride, 3-nitro-: ACTIVE

응용 분야

용도Manufacture of dyes for fabrics and color photography, intermediate in preparation of pharmaceuticals.

일반 설명Yellow to brown liquid. Unstable at room temperatures; requires refrigeration when not in use.

공급사29 곳

陕西缔都医药有限责任公司029-81124775 17791530730 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]
武汉欣扬瑞和化学科技有限公司18171205315; 18171205315 · [email protected]
上海辅欣医药科技有限公司+86-021-021-50872116 · [email protected]
武汉市聚舜化工有限公司027-02783261126 18971318572 · [email protected]

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