tert-Butanol → HCID 86745735, 화합물

HRID 1031224

반응식

HRID 1031224 반응식
C(O)(C)(C)C.[O:6]=[CH:7][C@@H:8]([C@H:10]([C@@H:12]([C@@H:14]([CH2:16][OH:17])[OH:15])[OH:13])[OH:11])[OH:9].[C:18]([O:29]C)(=[O:28])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27]>CO>[C:18]([OH:29])(=[O:28])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27].[O:6]=[CH:7][C@@H:8]([C@H:10]([C@@H:12]([C@@H:14]([CH2:16][OH:17])[OH:15])[OH:13])[OH:11])[OH:9]

참가 물질

5

반응물 3

HCID 6386tert-ButanolHCID 8050Methyl DecanoateHCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

생성물 1

HCID 86745735HCID 86745735, 화합물

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

25 ml of tertiary butanol was added to a mixture of 5.00 g (27.64 mM) of glucose and 1.03 g (5.55 mM) of methyl caprinate, and 100 mg of thermostable lipase derived from Candida antarctica (sp-382, manufactued by NOVO Co.) immobilized into an acrylic resin was further added. Then, they were refluxed under heating while stirring for 24 hours with an addition of 10 g of molecular sieves 5A as a methanol remover, to obtain glucose monocaprinate (C10 glucose ester).

후처리

  1. additionwas further added
  2. temperatureThen, they were refluxed
  3. temperatureunder heating

출처 및 근거

ORD 기록
ord-344f50ca68b04784888a853a933057d8
출처 데이터셋
uspto-grants-1992_04
특허 번호
US05109127

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