1-Chlorohexane → Hexyltrichlorosilane

HRID 1068506

반응식

C(P(CCCC)CCCC)CCC.Cl[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[Cl:21][SiH:22]([Cl:24])[Cl:23]>>[CH2:15]([Si:22]([Cl:24])([Cl:23])[Cl:21])[CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]

참가 물질

반응물 3

HCID 109921-Chlorohexane

HCID 13831Tributylphosphine

HCID 24811Trichlorosilane

생성물 1

HCID 13571Hexyltrichlorosilane수율 66.8%

반응 조건

온도: 150 °C

실험 절차

In a 25 ml oven dried stainless steel tube, 0.15 g (0.75 mmol) of tri-n-butylphosphine, 0.90 g (7.5 mmol) of 1-chlorohexane, and 5.08 g (37.5 mmol) of trichlorosilane were added under a dry nitrogen atmosphere. After sealing the cylinder with a valve, the reactor was maintained at 150° C. for 12 hrs. The resulting mixture was distilled to yield 1.1 g of n-hexyltrichlorosilane (bp; 215-219° C., yield; 65%).

후처리

distillationThe resulting mixture was distilled

출처 및 근거

ORD 기록: ord-2ec5a80fe7254d0484b7a147c6ae5bb6
출처 데이터셋: uspto-grants-2001_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06251057B1

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