Hydrochloric Acid → Cyclopentene

HRID 1072774

반응식

HRID 1072774 반응식
C(Cl)(C)(C)C.Cl.[CH:7]1(Cl)[CH2:11][CH2:10][CH2:9][CH2:8]1.C1([SiH](Cl)Cl)CCCC1.C1([Si:26]([Cl:29])([Cl:28])[Cl:27])CCCC1>>[CH:7]1[CH2:11][CH2:10][CH2:9][CH:8]=1.[Cl:27][SiH:26]([Cl:29])[Cl:28]

참가 물질

7

반응물 5

HCID 313Hydrochloric AcidHCID 10486tert-BUTYL CHLORIDE2회HCID 70252ChlorocyclopentaneHCID 84533TrichlorocyclopentylsilaneHCID 71344807Cyclopentyldichlorosilane

생성물 2

HCID 8882Cyclopentene수율 58.4%HCID 24811Trichlorosilane

실험 절차

The reaction was carried out under the same condition as in Example 3, except that the same amount of t-butyl chloride was used as the hydrogen chloride source. A mixture of cyclopentyl chloride and t-butyl chloride having the mixing ratio of 1:2 was reacted with metallic silicon at 280° C. to give 30.1 g of reaction products. The reaction products contained 6.2 g (39.1%) of cyclopentyldichlorosilane and 0.3 g (1.6%) of cyclopentyltrichlorosilane. There were not starting materials unreacted. As other by-products, 3.7 g (58.4%) of cyclopentene, 2.9 g of trichlorosilane and unconfirmed materials were obtained.

후처리

  1. customwas reacted with metallic silicon at 280° C.
  2. customto give
  3. custom30.1 g of reaction products

출처 및 근거

ORD 기록
ord-9b6b831658204195936c22d1f14da4cc
출처 데이터셋
uspto-grants-2005_06
특허 번호
US06911552B2

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