Ethanol → (3,5,5 Trimethyl hexyl) 4-aminobenzoate
반응식
[Na].C(O)C.[NH2:5][C:6]1[CH:16]=[CH:15][C:9]([C:10]([O:12][CH2:13][CH3:14])=[O:11])=[CH:8][CH:7]=1.[CH3:17][CH:18]([CH2:22][C:23]([CH3:26])([CH3:25])[CH3:24])CCO>C1CCCCC1>[NH2:5][C:6]1[CH:7]=[CH:8][C:9]([C:10]([O:12][CH2:13][CH2:14][CH:18]([CH3:17])[CH2:22][C:23]([CH3:26])([CH3:25])[CH3:24])=[O:11])=[CH:15][CH:16]=1참가 물질
6
실험 절차
Sodium metal (1 g cat.) was added to ethanol (30 mL) to give a solution which was added to a suspension of ethyl 4-aminobenzoate (175 g, 1.06 mol) and 3,5,5 trimethyl hexanol (200 g, 1.4 mol) in cyclohexane (300 mL). The suspension was heated under reflux for 24 hours with the azeotropic removal of ethanol.
후처리
- customto give a solution which
- temperatureThe suspension was heated
출처 및 근거
- ORD 기록
- ord-74ff96502e7f4c339282b0b43bcc57c1
- 출처 데이터셋
- uspto-grants-2006_10
- 특허 번호
- US07129204B2
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