Carbon Disulfide → HCID 13561953, 화합물

HRID 1249052

반응식

HRID 1249052 반응식
[CH2:1]1[C:13]2[NH:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH2:4][C@H:3]([C:14]([OH:16])=[O:15])[NH:2]1.[OH-].[K+].[CH2:19](Cl)[C:20]1[O:24][CH:23]=[CH:22][CH:21]=1.C(O)C1OC=CC=1.S(Cl)(Cl)=O.[C:37](=[S:39])=[S:38]>N1C=CC=CC=1.C(O)C>[CH2:19]([S:39][C:37]([N:2]1[C@@H:3]([C:14]([OH:16])=[O:15])[CH2:4][C:5]2[C:6]3[C:11](=[CH:10][CH:9]=[CH:8][CH:7]=3)[NH:12][C:13]=2[CH2:1]1)=[S:38])[C:20]1[O:24][CH:23]=[CH:22][CH:21]=1

참가 물질

9

반응물 6

HCID 6348Carbon DisulfideHCID 7361Furfuryl AlcoholHCID 14797Potassium HydroxideHCID 24386Thionyl ChlorideHCID 2195202-(Chloromethyl)furanHCID 675102D-1,2,3,4-Tetrahydronorharman-3-carboxylic acid

생성물 1

HCID 13561953HCID 13561953, 화합물

시약·촉매·용매 2

HCID 702Ethanol용매HCID 1049Pyridine용매

실험 절차

In the same manner as descsribed in Example 32, (3R)-1,2,3,4-tetrahydro-β-carboline-3-carboxylic acid (8.65 g), KOH (4.67 g), carbon disulfide (2.43 ml), 75% ethanol (120 ml) and furfuryl chloride which is prepared from furfuryl alcohol (9.24 g), thionyl chloride (12.34 g) and pyridine (8.94 g) are reacted and treated to give the title compound (2.31 g) as pale yellow powder.

후처리

  1. customare reacted
  2. additiontreated

출처 및 근거

ORD 기록
ord-4d04b1f0650b4fee9de48418bb2f4bae
출처 데이터셋
uspto-grants-1986_12
특허 번호
US04628057

연결된 노트

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