홈MCP워크벤치Skills
홈워크벤치알림마이페이지
llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
  1. 홈
  2. /반응

Hydrochloric Acid → Perylene

HRID 1413330
노트
인쇄 미리보기

반응식

HRID 1413330 반응식
C(O)(=O)CCCCCCCCCCCCCCCCC.[C:21]1(C(O)=O)[C:38]2=[C:39]3[C:28]([C:29]4[C:40]5[C:33](=[CH:34][CH:35]=[CH:36][C:37]2=5)[CH:32]=[CH:31][CH:30]=4)=[CH:27][CH:26]=[C:25](C(O)=O)[C:24]3=[C:23](C(O)=O)[C:22]=1C(O)=O.C(O)(=O)CCCCCCCCCCCCCCCCC.C(N)CCCCCCCCCCCCCCCCC.Cl>[K].C1(C(O)=O)C2=C3C(C4C5C(=CC=CC2=5)C=CC=4)=CC=C(C(O)=O)C3=C(C(O)=O)C=1C(O)=O.[OH-].[K+].C(O)(C)C>[CH:36]1[C:37]2=[C:40]3[C:29]([C:28]4[C:39]5[C:24](=[CH:23][CH:22]=[CH:21][C:38]2=5)[CH:25]=[CH:26][CH:27]=4)=[CH:30][CH:31]=[CH:32][C:33]3=[CH:34][CH:35]=1
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

9

반응물 4

HCID 313Hydrochloric AcidHCID 5281Stearic AcidHCID 15793OctadecylamineHCID 86737471HCID 86737471, 화합물

생성물 1

HCID 9142Perylene

시약·촉매·용매 4

HCID 3776Isopropanol용매
HCID 14797
Potassium Hydroxide
용매
2회
HCID 5462222Potassium용매
HCID 19063515Perylene-1,2,3,4-tetracarboxylic acid용매

실험 절차

27.4 parts of crude perylenetetracarboxylic dianhydride in the form of the potassium salt of perylenetetracarboxylic acid are dissolved in aqueous potassium hydroxide solution as described in Example 1. To this solution are added 2 parts of stearic acid, dissolved in 60 parts by volume of 1% potassium hydroxide solution. With stirring, the alkaline perylenetetracarboxylic acid/stearic acid solution is added dropwise in the course of 15 minutes at 60° C. to a suspension consisting of 1.4 parts of MgCl2.6H2O, 0.7 parts of stearylamine, 35 parts by volume of about 37% aqueous hydrochloric acid and 60 parts by volume of isopropanol. The formation of the anhydride imide is brought to completion by stirring the acid suspension for 31/2 hours at reflux temperature. The red pigment suspension is then filtered at about 70° C. The filter cake is washed neutral with cold water and dried in a vacuum cabinet at 80° C., affording 29.8 parts of a perylene pigment with properties as good as those of the pigment of Example 1.

후처리

  1. stirringby stirring the acid suspension for 31/2 hours
  2. temperatureat reflux temperature
  3. filtrationThe red pigment suspension is then filtered at about 70° C
  4. washThe filter cake is washed neutral with cold water
  5. customdried in a vacuum cabinet at 80° C.

출처 및 근거

ORD 기록
ord-87b70f3364c44a2c930935bdf9f06233
출처 데이터셋
uspto-grants-1981_02
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04250079

반응 노트

불러오는 중…

이 페이지에서참가 물질실험 절차후처리출처 및 근거반응 노트