Hydrochloric Acid → Di(tetrachlorophenyl)tetrachlorocyclopentadiene

HRID 1415487

반응식

HRID 1415487 반응식
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([Cl:8])=[C:4]([Cl:9])[C:3]=1[Cl:10].Cl[C:12]1(Cl)[C:16]([Cl:17])=[C:15]([Cl:18])[C:14]([Cl:19])=[C:13]1[Cl:20].[Cl-:22].[Al+3].[Cl-:24].[Cl-:25].[ClH:26]>>[Cl:1][C:2]1[C:3]([Cl:10])=[C:4]([Cl:9])[C:5]([Cl:8])=[C:6]([C:12]2([C:2]3[CH:7]=[C:6]([Cl:22])[C:5]([Cl:24])=[C:4]([Cl:25])[C:3]=3[Cl:26])[C:13]([Cl:20])=[C:14]([Cl:19])[C:15]([Cl:18])=[C:16]2[Cl:17])[CH:7]=1

참가 물질

5

반응물 4

HCID 313Hydrochloric AcidHCID 6478HexachlorocyclopentadieneHCID 124631,2,3,4-TetrachlorobenzeneHCID 6451240Aluminum(III) Chloride

생성물 1

HCID 54039303Di(tetrachlorophenyl)tetrachlorocyclopentadiene

실험 절차

A mixture of 1,2,3,4-tetrachlorobenzene, 130 grams (0.6 mole), hexachlorocyclopentadiene, 65 grams (0.24 mole), and aluminum chloride, 5 grams, was heated on a steam bath at 75°-90° centigrade until the evolution of hydrogen chloride stopped and the reaction mixture solidified. The purple solid was triturated with acetone to dissolve the aluminum chloride, filtered, washed with acetone and dried to give a tan, solid product.

후처리

  1. customThe purple solid was triturated with acetone
  2. dissolutionto dissolve the aluminum chloride
  3. filtrationfiltered
  4. washwashed with acetone
  5. customdried
  6. customto give a tan, solid product

출처 및 근거

ORD 기록
ord-b9208cc0342340e587b3093fb7374cf0
출처 데이터셋
uspto-grants-1977_01
특허 번호
US04005153

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