5-Tert-butyl-m-xylene → 2,6-Dimethyl-4-t-butyl-1-acryloylbenzene

HRID 1428456

반응식

HRID 1428456 반응식
[C:1]([C:5]1[CH:6]=[C:7]([CH3:12])[CH:8]=[C:9]([CH3:11])[CH:10]=1)([CH3:4])([CH3:3])[CH3:2].[C:13](Cl)(=[O:16])[CH:14]=[CH2:15].[Cl-].[Al+3].[Cl-].[Cl-]>ClCCl>[CH3:12][C:7]1[CH:6]=[C:5]([C:1]([CH3:4])([CH3:3])[CH3:2])[CH:10]=[C:9]([CH3:11])[C:8]=1[C:13](=[O:16])[CH:14]=[CH2:15]

참가 물질

5

반응물 3

HCID 73785-Tert-butyl-m-xyleneHCID 13140Acryloyl chlorideHCID 6451240Aluminum(III) Chloride

생성물 1

HCID 469134822,6-Dimethyl-4-t-butyl-1-acryloylbenzene

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

5-t-butylmetaxylene (0.5 mL), acryloyl chloride (120 mg), and aluminium chloride (150 mg) were reacted in dichloromethane (1.5 mL) at from −40° C. to room temperature for 2 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (120 mg).

후처리

  1. additionThe resultant was treated in the same manner

출처 및 근거

ORD 기록
ord-1f38244b93d54d9a9df49f23e0d57e56
출처 데이터셋
uspto-grants-2015_01
특허 번호
US08937091B2

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