1-Phenylnaphthalene → Acryloyl-1-phenylnaphthalene

HRID 1428464

반응식

HRID 1428464 반응식
[C:1]1([C:7]2[C:16]3[C:11](=[CH:12][CH:13]=[CH:14][CH:15]=3)[CH:10]=[CH:9][CH:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:17](Cl)(=[O:20])[CH:18]=[CH2:19].[Cl-].[Al+3].[Cl-].[Cl-]>ClCCl>[C:17]([C:8]1[CH:9]=[CH:10][C:11]2[C:16](=[CH:15][CH:14]=[CH:13][CH:12]=2)[C:7]=1[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)(=[O:20])[CH:18]=[CH2:19]

참가 물질

5

반응물 3

HCID 117951-PhenylnaphthaleneHCID 13140Acryloyl chlorideHCID 6451240Aluminum(III) Chloride

생성물 1

HCID 86673232Acryloyl-1-phenylnaphthalene수율 125.2%

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

1-phenylnaphthalene (204 mg), acryloyl chloride (200 mg), and aluminium chloride (290 mg) were reacted in dichloromethane (1.5 mL) at from −40° C. to room temperature for 2 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (323 mg).

후처리

  1. additionThe resultant was treated in the same manner

출처 및 근거

ORD 기록
ord-d3ef5e2ceed241289f186007c662443e
출처 데이터셋
uspto-grants-2015_01
특허 번호
US08937091B2

연결된 노트

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