Catechol → HCID 131719865, 화합물

HRID 1451992

반응식

HRID 1451992 반응식
[C:1]1([C:3](=[CH:5][CH:6]=[CH:7][CH:8]=1)O)[OH:2].[NH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][NH2:22].[O:23]=O>ClCC(Cl)CCl.ClC=C(Cl)Cl>[C:16]1([C:5]2[C:6](=[O:23])[CH:7]=[CH:8][C:1](=[O:2])[CH:3]=2)[CH:17]=[CH:18][CH:19]=[CH:20][CH:21]=1.[NH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][NH2:22]

참가 물질

6

반응물 3

HCID 289CatecholHCID 977Oxygen2회HCID 177271,12-Dodecanediamine

생성물 1

HCID 131719865HCID 131719865, 화합물

시약·촉매·용매 2

HCID 6575Trichloroethylene용매2회HCID 72851,2,3-Trichloropropane용매

실험 절차

About 14.54 g (0.0782 mol) 2-phenyl-hydrooquinone, about 0.2 g (0.0018 mol) catechol (chemical name 1,2-dihydroxybenzene) and about 16 g (0.08 mol) 1,12diaminododecane were dissolved in a solvent mixture comprising of about 30 mL of 1,2,3trichloropropane and 60 mL of trichloroethylene. Oxygen was then passed at a flow rate of about 50 cc/min through the solution for about one hour. About 0.2 g of cupric sulfate was then added to the reaction mixture. Oxygen flow was reinstated for about an additional two hours. At the end of the polymerization reaction most of the trichloroethylene was removed under high vacuum, without raising the temperature above 35° C. This solution of poly-(2-phenyl-benzoquinone-1,12-diaminododecane) polymer can be used directly for coating purposes.

후처리

  1. customwas reinstated for about an additional two hours
  2. customwas removed under high vacuum
  3. temperaturewithout raising the temperature above 35° C

출처 및 근거

ORD 기록
ord-abe3001167674f86ba1595956f75f223
출처 데이터셋
uspto-grants-1997_02
특허 번호
US05606010

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