Sodium Chloride → 4-Octen-3-one
반응식
C(Cl)C=C(C)C.[OH-:7].[Na+].[CH3:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16]CC.[Cl-].[Na+]>[Cl-].C([N+](C)(C)C)CCCCCCCCCCC.O.CC(C)=O>[CH3:9][CH2:10][C:11](=[O:7])[CH:12]=[CH:13][CH2:14][CH2:15][CH3:16]참가 물질
8
실험 절차
By using the same reaction vessel as used in Example 1, 10.45 g of prenyl chloride, 34.8 ml of acetone, 20.3 g of a 65 % aqueous caustic soda solution, 5 ml of n-decane and 0.264 g of lauryl trimethylammonium chloride were added into the vessel, and then the mixture was allowed to react for 12 hours at 30°C. with vigorous stirring. After the reaction was completed, 40 ml of water was added to the resultant solution to dissolve the sodium chloride. Methyl heptenone was produced as determined by using gas chromatography and the yield was 51 % calculated on the theoretical value.
후처리
- additionwere added into the vessel
- customto react for 12 hours at 30°C. with vigorous stirring
출처 및 근거
- ORD 기록
- ord-a5927956efd9445caf5da00b502a3e76
- 출처 데이터셋
- uspto-grants-1976_09
- 특허 번호
- US03983175
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