Oxalic Acid → Zirconium phosphate

HRID 1939850노트

반응식

HRID 1939850 반응식
C(O)(=O)C(O)=O.[N+]([O-])(O)=O.[N+]([O-])(O)=O.O=[Zr:16].[N+]([O-])([O-])=O.[Na+].[P:22](=[O:26])([OH:25])([OH:24])[OH:23].[OH-].[Na+]>>[P:22]([O-:26])([O-:25])([O-:24])=[O:23].[Zr+4:16].[P:22]([O-:26])([O-:25])([O-:24])=[O:23].[P:22]([O-:26])([O-:25])([O-:24])=[O:23].[P:22]([O-:26])([O-:25])([O-:24])=[O:23].[Zr+4:16].[Zr+4:16]

참가 물질

6

반응물 5

HCID 971Oxalic AcidHCID 1004Phosphoric AcidHCID 14798Sodium HydroxideHCID 24268Sodium NitrateHCID 83761Zirconyl nitrate

생성물 1

HCID 160986Zirconium phosphate

실험 절차

Oxalic acid is added to an aqueous solution of zirconium oxynitrate and sodium nitrate with stirring and then phosphoric acid is further added. The reaction mixture is adjusted to pH 3.5 with an aqueous sodium hydroxide solution and refluxed with heating for 78 hours. The precipitate is subjected to filtration, washing with water, drying and grinding to obtain zirconium phosphate [NaZr2 (PO4)3 ] having a network structure. The product is immersed in an aqueous solution containing silver ion at a suitable concentration to obtain the compound represented by the formula [1].

후처리

  1. temperaturerefluxed
  2. temperaturewith heating for 78 hours
  3. filtrationThe precipitate is subjected to filtration
  4. washwashing with water
  5. customdrying
  6. customgrinding

출처 및 근거

ORD 기록
ord-a969be2cb21343c2920c2667e40cbbb0
출처 데이터셋
uspto-grants-1997_12
특허 번호
US05698229

반응 노트

불러오는 중…