Imidazole → Ethyl N-phenylcarbamate

HRID 2052544

반응식

HRID 2052544 반응식
O=C=[N:3][CH:4]1[CH2:13][C:12](C)(C)[CH2:11][C:6](C)(CN=C=O)[CH2:5]1.C1(O)C=CC=CC=1.N1C=CN=C1.CCO[CH2:32][CH2:33][O:34][C:35](C)=[O:36].C(N(CCO)CCO)CCC.C(C1OC1)Cl.C(OS(OCC)(=O)=O)C>C(O)C>[C:4]1([NH:3][C:35]([O:34][CH2:33][CH3:32])=[O:36])[CH:13]=[CH:12][CH:11]=[CH:6][CH:5]=1

참가 물질

9

반응물 7

HCID 795ImidazoleHCID 996PhenolHCID 6163Diethyl SulfateHCID 7620N-ButyldiethanolamineHCID 7835EpichlorohydrinHCID 8095Glycol monoethyl ether acetateHCID 169132Isophorone diisocyanate

생성물 1

HCID 7591Ethyl N-phenylcarbamate

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

1.0 mol of isophorone diisocyanate is dissolved in 2.2 mol of phenol at 95°-100° C. after the addition of 0.5 imidazole. The mixture is kept as a liquid by the addition of 200 ml of ethylglycol acetate. 0.9 mol of butyldiethanolamine are added after a reaction time of four hours and the mixture is then distilled at a reaction temperature of 120° C. to remove everything which distils off at a vacuum of 5 torr. The residue is then dissolved in 200 ml of ethylglycol acetate and 400 ml of ethanol and quaternised at 60°-70° C., first with 0.5 mol of epichlorohydrin for three hours and then with 0.5 mol of diethylsulphate. The readily soluble cationic polyurethane with phenylurethane end groups obtained in this way is made up to a volume of 2000 ml with methanol and then stored at temperatures below 10° C.

후처리

  1. distillationthe mixture is then distilled at a reaction temperature of 120° C.
  2. customto remove everything which
  3. customdistils off at a vacuum of 5 torr
  4. dissolutionThe residue is then dissolved in 200 ml of ethylglycol acetate

출처 및 근거

ORD 기록
ord-181fb0fcddd64774a06e241f1449d47a
출처 데이터셋
uspto-grants-1980_01
특허 번호
US04186014

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