Hydrochloric Acid → 2-Ethyl-2-n-butyl-11-phenyl-11-amino-undeca-4,8-dienal-oxime

HRID 223646

반응식

HRID 223646 반응식
[CH2:1]([C:5]1([CH2:23][CH3:24])[CH2:16][CH:15]=[CH:14][CH2:13][CH2:12][CH:11]=[CH:10][CH2:9][CH:8]([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)[N:7]=[CH:6]1)[CH2:2][CH2:3][CH3:4].Cl.[NH2:26][OH:27].Cl>O>[CH2:1]([C:5]([CH2:23][CH3:24])([CH2:16][CH:15]=[CH:14][CH2:13][CH2:12][CH:11]=[CH:10][CH2:9][CH:8]([C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1)[NH2:7])[CH:6]=[N:26][OH:27])[CH2:2][CH2:3][CH3:4]

참가 물질

5

반응물 3

HCID 313Hydrochloric AcidHCID 443297Hydroxyamine hydrochlorideHCID 545232413-Ethyl-3-n-butyl-12-phenyl-1-aza-1,5,9-cyclododecatriene

생성물 1

HCID 736789192-Ethyl-2-n-butyl-11-phenyl-11-amino-undeca-4,8-dienal-oxime수율 100%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

The procedure described in Example 1(b) is repeated, except that 283.4 g (0.875 mol) of 3-n-butyl-3-ethyl-12-phenyl-1-aza-1,5,9-cyclododecatriene, 60.8 g (0.87 mol) of hydroxylamine hydrochloride, 50 ml of concentrated hydrochloric acid and 250 ml of water are used. Working up yields 310 g (0.87 mol) of 2-n-butyl-2-ethyl-11-phenyl-11-amino-undeca-4,8-dienal oxime; yield 99.5% of theory.

출처 및 근거

ORD 기록
ord-811b847bcc4049f289519692750ea915
출처 데이터셋
uspto-grants-1982_10
특허 번호
US04355177

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