Water → Citronellyl Acetate

HRID 236877

반응식

HRID 236877 반응식
[C:1]([O:4][C:5](=[O:7])[CH3:6])(=O)[CH3:2].[CH3:8][CH2:9][CH2:10]CCC.O.N1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1>>[C:5]([O:4][CH2:1][CH2:2][CH:17]([CH2:18][CH2:19][CH:20]=[C:9]([CH3:10])[CH3:8])[CH3:16])(=[O:7])[CH3:6]

참가 물질

5

반응물 4

HCID 962WaterHCID 1049PyridineHCID 7918Acetic AnhydrideHCID 8058Hexane

생성물 1

HCID 9017Citronellyl Acetate

실험 절차

To 15.6 g (0.1 mol) d1-citronellol in 20 ml of dry pyridine under nitrogen is added 11.3 ml (0.12 mol) of acetic anhydride. The reaction is stirred about 48 hours and then ice is added. After one hour, the reaction is poured into hexane and water. The organic phase is washed with 5% HCl, 2M sodium carbonate, and saturated NaCl solutions, dried over calcium sulfate and solvent removed to yield dl-citronellyl acetate.

후처리

  1. additionice is added
  2. waitAfter one hour
  3. washThe organic phase is washed with 5% HCl, 2M sodium carbonate, and saturated NaCl solutions
  4. dry with materialdried over calcium sulfate and solvent
  5. customremoved

출처 및 근거

ORD 기록
ord-3ddca04c8f4a4b5885d7d10c1ae64d52
출처 데이터셋
uspto-grants-1979_06
특허 번호
US04158096

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