Azobisisobutyronitrile → Styrenesulfonic Acid Allylhexafluoro-Isopropanol

HRID 254138

반응식

HRID 254138 반응식
[CH:1]([S:9]([O-:12])(=[O:11])=[O:10])=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[Na+].N(C(C)(C)C#N)=NC(C)(C)C#N.[CH2:26]([C:29]([OH:38])([C:34]([F:37])([F:36])[F:35])[C:30]([F:33])([F:32])[F:31])[CH:27]=[CH2:28]>CS(C)=O>[CH:1]([S:9]([OH:12])(=[O:10])=[O:11])=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH2:26]([C:29]([OH:38])([C:30]([F:32])([F:33])[F:31])[C:34]([F:35])([F:36])[F:37])[CH:27]=[CH2:28]

참가 물질

5

반응물 3

HCID 6547AzobisisobutyronitrileHCID 3288704-Penten-2-ol, 1,1,1-trifluoro-2-(trifluoromethyl)-HCID 53627496Sodium styrenesulfonate

생성물 1

HCID 131728620Styrenesulfonic Acid Allylhexafluoro-Isopropanol

시약·촉매·용매 1

HCID 679Dimethyl Sulfoxide용매2회

실험 절차

19 g of sodium styrenesulfonate (SSNa) (available from Sigma-Aldrich Corp.) and 1 g of 2-Allylhexafluoro-isopropanol are fully dissolved in 0.24 L of dimethylsulfoxide (DMSO) with heating. Then, 0.1 g of azobisisobutyronitrile (AIBN) is added dropwise to the DMSO solution. The monomers are polymerized for 24 hours or more. The polymerization is carried out varying the content of the allylhexafluoro-isopropanol (2, 5, 10, and 20 wt %).

후처리

  1. temperaturewith heating
  2. customThe monomers are polymerized for 24 hours or more

출처 및 근거

ORD 기록
ord-ed02a1056370470d86ee721b3d2d6bbb
출처 데이터셋
uspto-grants-2011_01
특허 번호
US07875208B2

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