Hydrochloric Acid → Tri-n-decylcarbinol

HRID 2583

반응식

HRID 2583 반응식
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[Mg].C(=O)([O:17][CH2:18][CH3:19])OCC.Cl>C(OCC)C>[CH2:2]([C:18]([CH2:19][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[OH:17])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

참가 물질

6

반응물 4

HCID 313Hydrochloric AcidHCID 7766Diethyl CarbonateHCID 81731-BromodecaneHCID 5462224Magnesium

생성물 1

HCID 19690419Tri-n-decylcarbinol

시약·촉매·용매 1

HCID 3283Diethyl Ether용매2회

반응 조건

온도
30 °C

실험 절차

Three moles of 1-bromodecane was slowly added to 3 moles of magnesium turnings in 0.6 liters of anhydrous ethyl ether (nitrogen atmosphere). One mole of diethyl carbonate in 0.151 anhydrous ethyl ether was slowly added to the mixture. After stirring for one hour at 30° C., the mixture was slowly poured into 1.8 liters of a cold 10% HCl solution. The organic layer was dried with magnesium sulfate and the ethyl ether evaporated off to give tri-n-decylcarbinol.

후처리

  1. dry with materialThe organic layer was dried with magnesium sulfate
  2. customthe ethyl ether evaporated off

출처 및 근거

ORD 기록
ord-5831ca84c85c45188e821732a2150987
출처 데이터셋
uspto-grants-1998_03
특허 번호
US05728907

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