1-Butanol → 2-Hydroxydecyl-butyl ether

HRID 267607

반응식

HRID 267607 반응식
[O:1]1[CH:3]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:2]1.[Na].C1OC1.[CH2:16]([OH:20])[CH2:17][CH2:18][CH3:19]>C[O-].[Na+]>[OH:1][CH:3]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:2][O:20][CH2:16][CH2:17][CH2:18][CH3:19]

참가 물질

6

반응물 4

HCID 2631-ButanolHCID 6354Ethylene OxideHCID 169931,2-EpoxydecaneHCID 5360545Sodium

생성물 1

HCID 104664152-Hydroxydecyl-butyl ether

시약·촉매·용매 1

HCID 10942334Sodium Methoxide촉매

실험 절차

As described in Example 1, 1 mol of 1,2-epoxydecane was caused to react with 5 times the molar quantity of n-butanol and 0.04 gm-atom of sodium. After distillation of the excess alcohol, the reaction with 10 mols of ethylene oxide was conducted in an autoclave under the conditions described in Example 1, except for the addition of the sodium methylate catalyst. The product thus obtained had a cloud point of 64°C.

후처리

  1. distillationAfter distillation of the excess alcohol
  2. customThe product thus obtained

출처 및 근거

ORD 기록
ord-5d32d71825f34bd8a73662fac1561a93
출처 데이터셋
uspto-grants-1976_03
특허 번호
US03943178

연결된 노트

불러오는 중…