Toluene → Allylamine

HRID 330598

반응식

HRID 330598 반응식
[CH2:1]([O:3][SiH:4]([O:8][CH2:9]C)[O:5][CH2:6]C)C.CO[SiH](OC)OC.C1(C)C=CC=CC=1.[NH2:25][CH2:26][CH2:27][CH2:28][Si](OC)(OC)OC>CC1C=CC(C)=CC=1>[CH2:26]([NH2:25])[CH:27]=[CH2:28].[CH3:1][O:3][SiH:4]([O:8][CH3:9])[O:5][CH3:6]

참가 물질

7

반응물 4

HCID 1140TolueneHCID 13830TriethoxysilaneHCID 17215TrimethoxysilaneHCID 83756Aminopropyltrimethoxysilane

생성물 2

HCID 7853AllylamineHCID 17215Trimethoxysilane

시약·촉매·용매 1

HCID 7809P-Xylene용매

실험 절차

Example 1 was repeated except that the 41 grams of triethoxy silane was replaced with 30.6 grams of trimethoxy silane (0.25 mole) and toluene was used as a solvent instead of p-xylene, with other conditions remaining the same. After the completion of the reaction, the reaction mixture was subjected to gas chromatography analysis. It was found that gamma-aminopropyl trimethoxy silane was obtained in a yield of 70% on an allylamine basis, while the yield of beta-amminopropyl trimethoxy silane was 0.9% on an a trimethoxy silane basis.

후처리

  1. customAfter the completion of the reaction

출처 및 근거

ORD 기록
ord-e3577c4eabb146a69b54c6f965de7145
출처 데이터셋
uspto-grants-1990_01
특허 번호
US04897501

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