Sodium Hydroxide → 1,2-Bis(3-chlorophenyl)hydrazine

HRID 465160

반응식

HRID 465160 반응식
[OH-].[Na+].[Cl:3][C:4]1[CH:5]=[C:6]([N+:10](=[N:12][C:13]2[CH:18]=[CH:17][CH:16]=[C:15]([Cl:19])[CH:14]=2)[O-])[CH:7]=[CH:8][CH:9]=1>[Ni].CO.O>[Cl:3][C:4]1[CH:5]=[C:6]([NH:10][NH:12][C:13]2[CH:18]=[CH:17][CH:16]=[C:15]([Cl:19])[CH:14]=2)[CH:7]=[CH:8][CH:9]=1

참가 물질

6

반응물 2

HCID 14798Sodium HydroxideHCID 2609473,3'-Dichloroazoxybenzene

생성물 1

HCID 2579191,2-Bis(3-chlorophenyl)hydrazine수율 89%

시약·촉매·용매 3

HCID 935Nickel촉매HCID 887Methanol용매HCID 962Water용매

반응 조건

온도
10 °C

실험 절차

1.2 g of sodium hydroxide and 0.25 g of Raney nickel are added to a suspension of 53.4 g of 3,3'-dichloroazoxybenzene in 60 ml of methanol and 15 ml of water and the hydrogenation reaction is carried out under a hydrogen pressure of 10 bars. After 90 minutes the mixture is cooled to 10° C. and the product is isolated by filtration. 3,3'-Dichlorohydrazobenzene is obtained in a yield of 89% of theory.

후처리

  1. customthe hydrogenation reaction
  2. customthe product is isolated by filtration

출처 및 근거

ORD 기록
ord-92967de8b5334f19bc63a49c9d179edd
출처 데이터셋
uspto-grants-1985_10
특허 번호
US04550207

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