Nitric Acid → 5-Aminoacenaphthene

HRID 46612

반응식

HRID 46612 반응식
[N+:1]([C:4]1[C:14]2[C:15]3[C:7]([CH2:8][CH2:9][C:10]=3[CH:11]=[CH:12][CH:13]=2)=[CH:6][CH:5]=1)([O-])=O.C1C2=C3C(=CC=C2)C=CC=C3C1.[N+]([O-])(O)=O.[Sn].NN>Cl.[Ni].C(O)C.C(O)(=O)C>[NH2:1][C:4]1[C:14]2[C:15]3[C:7]([CH2:8][CH2:9][C:10]=3[CH:11]=[CH:12][CH:13]=2)=[CH:6][CH:5]=1

참가 물질

10

반응물 5

HCID 944Nitric AcidHCID 6734AcenaphtheneHCID 9321HydrazineHCID 117695-NitroacenaphtheneHCID 5352426Tin atom

생성물 1

HCID 625475-Aminoacenaphthene

시약·촉매·용매 4

HCID 935Nickel촉매HCID 176Acetic Acid용매HCID 313Hydrochloric Acid용매HCID 702Ethanol용매

실험 절차

5-Nitroacenaphthene is made by nitrating acenaphthene with nitric acid in the presence of acetic acid according to the method of Rowe and Davies, J. Chem. Soc. 117, 1346 (1920). Standard reduction methods using tin or stannous chloride in hydrochloric acid or by using Raney nickel with ethanol or hydrazine produces 5-aminoacenaphthene.

출처 및 근거

ORD 기록
ord-1a06f9ffbc2c46afaf47b657be09d7f6
출처 데이터셋
uspto-grants-1979_11
특허 번호
US04174342

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