Hydrochloric Acid → 9,9'-Bianthryl

HRID 47175

반응식

HRID 47175 반응식
Cl.[CH:2]1[C:15]2[C:14](=O)[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[CH2:7][C:6]=2[CH:5]=[CH:4][CH:3]=1>[Zn].C(O)(=O)C>[CH:2]1[C:15]2[C:6](=[CH:7][C:8]3[C:13]([C:14]=2[C:7]2[C:8]4[C:13]([CH:14]=[C:15]5[C:6]=2[CH:5]=[CH:4][CH:3]=[CH:2]5)=[CH:12][CH:11]=[CH:10][CH:9]=4)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1

참가 물질

5

반응물 2

HCID 313Hydrochloric AcidHCID 7018Anthrone

생성물 1

HCID 661059,9'-Bianthryl

시약·촉매·용매 2

HCID 23994Zinc촉매HCID 176Acetic Acid용매

실험 절차

After hydrochloric acid was added to an acetic acid solution of anthrone, it was refluxed upon addition of zinc. Thereafter it was refined in accordance with an ordinary method to obtain 9,9′-bianthryl. After it was added little by little to a melt of aluminum chloride and sodium chloride, the reaction mixture was poured into diluted hydrochloric acid and a solids constituent was collected. The solids constituent thus obtained was refined in accordance with an ordinary method to obtain target dibenzo[a,o]perylene.

출처 및 근거

ORD 기록
ord-09a1edf32dea46fb8b70e9767bbae5d4
출처 데이터셋
uspto-grants-2004_03
특허 번호
US06699594B1

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