Palmitic Acid → Oleic Acid

HRID 54719

반응식

HRID 54719 반응식
O=[CH:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])O)O)O)O.[CH3:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][C:24](O)=[O:25].[CH3:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38]CC(O)=[O:41].[CH3:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56]C(O)=O.CCCCCCCCCCCCCCCC(O)=[O:76].CCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCCCC(O)=O>>[CH3:24][CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17]/[CH:16]=[CH:15]\[CH2:14][CH2:13][CH2:2][CH2:3][CH2:5][CH2:7][CH2:9][C:11]([OH:12])=[O:41].[CH3:38][CH2:37][CH2:36][CH2:35][CH2:34]/[CH:33]=[CH:32]\[CH2:31]/[CH:30]=[CH:29]\[CH2:28][CH2:27][CH2:2][CH2:3][CH2:5][CH2:7][CH2:9][C:11]([OH:12])=[O:25].[CH3:56][CH2:55][CH2:54][CH2:53][CH2:52]/[CH:51]=[CH:50]\[CH2:49]/[CH:48]=[CH:47]\[CH2:46]/[CH:45]=[CH:44]\[CH2:43]/[CH:2]=[CH:3]\[CH2:5][CH2:7][CH2:9][C:11]([OH:12])=[O:76]

참가 물질

11

반응물 8

HCID 985Palmitic AcidHCID 3893Lauric AcidHCID 5281Stearic AcidHCID 10465Heptadecanoic AcidHCID 10467Eicosanoic AcidHCID 11005Myristic AcidHCID 13849Pentadecanoic AcidHCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

생성물 3

HCID 444899Arachidonic Acid수율 0.7%HCID 445639Oleic Acid수율 12.3%HCID 5280450Linoleic Acid수율 2%

실험 절차

At the end of the six-week period, the second group of 5 rats was switched to a diet of menhaden fish oil (35% of total calories), protein (about 25% of total calories) and dextrose (remainder of total calories) for two weeks with vitamins and minerals continued as before. The menhaden fish oil was found by analysis to contain the following percentages of fatty acids (total fatty acid basis): 0.2% C12:0, 10.3% C14:0, 1.1% C15:0, 20.0% C16:0, 1.2% C17:0, 3.4% C18:0, 2.1% C20:0, 14.8% C16:1, 0.3% C17:1, 12.3% C18:1, 2.6% C20:1, 0.6% C22:1, 0.2% C24:1, 1.6% C16:2, 2.0% C18:2, 3.7% C18:3, 0.5% C20:2, 0.4% C20:3, 0.7% C20:4, 9.8% C20:5, 1.8% C22:5, 6.1% C22:6 and 1.6% unknown and C19:1 alcohol, providing totals of 38.3% saturated fatty acid and 26.6% polyunsaturated fatty acid. At the end of the two-week period, the five rats of this group were sacrificed and determinations were made as described below.

출처 및 근거

ORD 기록
ord-bf6163deb1404b9bac3948ff97b1f44a
출처 데이터셋
uspto-grants-1997_04
특허 번호
US05622991

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