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Silica → Quaternium 18-bentonite

HRID 614193
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HRID 614193 반응식
[Si](=O)=[O:2].[O-2:4].[Al+3:5].[O-2:6].[O-2:7].[Al+3:8].[O-2].[Mg+2].[O-2].[Ca+2].C1CCCCCC(=O)OCCOC(=O)CCCCC1.O.[O-2].[O-2].[O-2].[O:36]=[Si:37]=[O:38].O=[Si]=O.O=[Si]=O.O=[Si]=O.[Al+3].[Al+3].[Ca].[Na].[O-2].[Na+].[Na+]>O.[Fe]>[OH2:2].[O:4]=[Al:5][O:6][Al:8]=[O:7].[O:36]=[Si:37]=[O:38]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

12

반응물 9

HCID 24261Silica4회HCID 61014Ethylene brassylateHCID 73971Sodium oxide2회HCID 5360545SodiumHCID 5460341CalciumHCID 6850728Calciumoxide3회HCID 6850729Magnesium monoxide4회
HCID 9989226
Alumina
4회
HCID 71586775Bentonite2회

생성물 1

HCID 517273Quaternium 18-bentonite

시약·촉매·용매 2

HCID 23925Iron촉매2회HCID 962Water용매4회

실험 절차

As examples of such useful materials mention may be made of aluminum magnesium silicates such as attapulgites, such as "Pharmasorb" trade name of Englehard Minerals and Chemicals Corporation for an activated attapulgite typically containing about 67.0% silicon dioxide, 12.5% aluminum oxide, 11.0% magnesium oxide, 4.0% ferric oxide, 2.5% calcium oxide and 3.0% others; "Mineral Colloid BP" trade name of Georgia Kaolin Company for a highly refined montmorillonite, a naturally occurring colloid, light amber in color, fine thin flakes or microgranules, insoluble in water and organic solvents but dispersing in water to form a colloidal suspension, pH around 8.5-9.5, typically containing about 58.2% silicon dioxide, 23.1% aluminum oxide, 4.0% ferric oxide, 2.5% magnesium oxide and other oxides; "Astra-tone 40" trade name of Georgia Kaolin Company for an organic-modified montmorillonite, a light buff powder; "Gelwhite L" trade name of Georgia Kaolin Company for a white montmorillonite with very low iron content, calcium and sodium being the major exchangeable cations, microgranular in form, insoluble in water and organic solvents but dispersing easily in water to form a colloidal suspension, pH about 8.5-9.5, typically containing 60.8% silicon dioxide, 21.5% aluminum oxide, 3.62% magnesium oxide, 0.9% ferric oxide, 2.21% calcium oxide, 1.30% sodium oxide, as well as other compounds; "Gelwhite GP" trade name of Georgia Kaolin Company for a white purified colloidal montmorillonite with predominantly sodium ions in exchange positions, dispersing readily in water to form a translucent gel, pH about 9.5-10, typical chemical analysis indicating 58.6% silicon dioxide, 21.2% aluminum oxide, 4.07% sodium oxide, 3.79% magnesium oxide, 2.42% calcium oxide, 0.97% ferric oxide, as well as other compounds; and "Bentolite" trade name of Georgia Kaolin Company for a white bentonite treated to eliminate the major portion of iron and other color producing impurities, e.g., "Bentolite L", pH about 7, a white powder typically containing 71.65% silicon dioxide, 15.67% aluminum oxide, 3.64% magnesium oxide, 1.66% calcium oxide, 0.34% ferric oxide, as well as other oxides, "Bentolite L- 2", a white powder, pH about 7.0, typically containing about 71.53% silicon dioxide, 15.39% aluminum oxide, 3.63% magnesium oxide, 1.66% calcium oxide, 0.72% ferric oxide, as well as other oxides, and "Bentolite H", a white powder, pH about 9.5, typically containing 69.20% silicon dioxide, 14.50% aluminum oxide, 3.35% magnesium oxide, 1.05% calcium oxide, 0.66% ferric oxide, as well as other oxides; synthetic clays such as "Barasym - SMM -- Na+ " trade name of National Lead Company, Baroid Division, for a synthetic muscovite - mica - interstratified montmorillonite with sodium surface charge, "Barasym - SMM -- K+ " trade name of National Lead Company, Baroid Division, for a synthetic muscovite - mica - interstratified montmorillonite with potassium surface charge, "Saponite" trade name of National Lead Company, Baroid Division, for a synthetic magnesium aluminum silicate clay, "Lithium Synthetic Hectorite SMH-3" trade name of National Lead Company, Baroid Division, for a synthetic magnesium fluorosilicate polymer with lithium hydroxide surface hectorite clay, "Sodium Synthetic Hectorite MSL-306" trade name of National Lead Company, Baroid Division, for a synthetic magnesium fluorosilicate polymer with sodium hydroxide surface hectorite clay, etc.

후처리

  1. customto form a colloidal suspension, pH around 8.5-9.5
  2. customto form a colloidal suspension, pH about 8.5-9.5
  3. custom"Gelwhite GP" trade name of Georgia Kaolin Company for a white purified colloidal montmorillonite with predominantly sodium ions in exchange positions
  4. additiondispersing readily in water
  5. customto form a translucent gel, pH about 9.5-10, typical chemical analysis

출처 및 근거

ORD 기록
ord-bd4507c4561d47e19c598ea76436050a
출처 데이터셋
uspto-grants-1979_03
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04144065

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