Water → Acetophenone

HRID 621830

반응식

HRID 621830 반응식
[C:1]1([CH:7]([CH3:9])[CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(C1C=CC(C(C)C)=CC=1)(C)C.[CH3:22][C:23](C)([C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)[OH:24].[OH2:32]>>[C:23]([C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)(=[O:24])[CH3:22].[O-:32][OH:24].[C:1]1([CH:7]([CH3:9])[CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

참가 물질

6

반응물 4

HCID 962WaterHCID 7406Cumene2회HCID 74861,4-DiisopropylbenzeneHCID 120532-Phenyl-2-propanol

생성물 2

HCID 7410AcetophenoneHCID 53627471Cumen hydroperoxide

실험 절차

Using 79.9 g (0.665 mole) of cumene in lieu of p-diisopropylbenzene, oxidation was carried out in the same apparatus and under the same conditions as those employed in Example 1. The reaction product obtained subsequent to its water washing and drying was an oily matter whose weight was 79.6 g. According to results of a high-performance liquid chromatographic analysis, the oily matter was found to contain 3.1 g (0.026 mole; conversion: 96.1%) of cumene and 75.3 g (0.553 mole; yield: 83.2 mole %) of dimethylphenylcarbinol. Acetophenone or cumene hydroperoxide was not formed practically.

후처리

  1. customdrying
  2. customto results of a high-performance liquid chromatographic analysis

출처 및 근거

ORD 기록
ord-2fb7bffb1d064be3b513c787f38a15b1
출처 데이터셋
uspto-grants-1989_04
특허 번호
US04825007

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