Hydrochloric Acid → Phenylphosphonic Acid

HRID 651937노트

반응식

HRID 651937 반응식
[C:1]1([P:7]([OH:9])[OH:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH-].[Na+].[O-:12][Mn](=O)(=O)=O.[K+].P(O)O.Cl.S(=O)(O)[O-].[Na+]>CC(C)=O.O>[C:1]1([P:7](=[O:12])([OH:9])[OH:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

참가 물질

9

반응물 6

HCID 313Hydrochloric AcidHCID 14798Sodium HydroxideHCID 72903Phenylphosphinic acidHCID 516875Potassium PermanganateHCID 3014827Phosphonous acidHCID 23665763Sodium Bisulfite

생성물 1

HCID 15295Phenylphosphonic Acid

시약·촉매·용매 2

HCID 180Acetone용매HCID 962Water용매3회

실험 절차

To a solution of phenylphosphonous acid (1 g, 0.007 mole) in acetone (10 ml) and water (10 ml) was added a solution of sodium hydroxide (0.281 gm, 0.007 mole) in water (10 ml) until a pH of about 7 was reached. A solution of KMnO4 (0.663 g, 0.007 mole) in water (10 ml) was added slowly to the vigorously stirred solution of phosphonous acid at 20°-25° C. After the addition (5 minutes), the reaction mixture was stirred for 5 minutes at ambient temperature and acidified with concentrated HCl acid until a pH of 1 was reached. Saturated sodium bisulfite solution was added to the reaction mixture thereby resulting in formation of a precipitate.

후처리

  1. additionAfter the addition (5 minutes)
  2. customthereby resulting in formation of a precipitate

출처 및 근거

ORD 기록
ord-ca7a4adde4924475bf02a84825b2c556
출처 데이터셋
uspto-grants-1987_06
특허 번호
US04670193

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