Sodium Hydroxide → Acifluorfen sodium

HRID 65331

반응식

HRID 65331 반응식
[Cl:1][C:2]1[CH:20]=[C:19]([C:21]([F:24])([F:23])[F:22])[CH:18]=[CH:17][C:3]=1[O:4][C:5]1[CH:6]=[CH:7][C:8]([N+:14]([O-:16])=[O:15])=[C:9]([CH:13]=1)[C:10]([OH:12])=[O:11].[OH-].[Na+:26]>CO>[Cl:1][C:2]1[CH:20]=[C:19]([C:21]([F:22])([F:23])[F:24])[CH:18]=[CH:17][C:3]=1[O:4][C:5]1[CH:6]=[CH:7][C:8]([N+:14]([O-:16])=[O:15])=[C:9]([CH:13]=1)[C:10]([O-:12])=[O:11].[Na+:26]

참가 물질

4

반응물 2

HCID 14798Sodium HydroxideHCID 44073Acifluorfen

생성물 1

HCID 44072Acifluorfen sodium수율 105.4%

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoic acid (1.7 g, 0.0047 mole) is dissolved in methanol (25 ml) and sodium hydroxide (4.7 ml of 1N NaOH in methanol, 0.0047 mole) is added rapidly. The solvent is then removed in vacuo to give 1.9 g of product that decomposes at 217° C.

후처리

  1. customThe solvent is then removed in vacuo

출처 및 근거

ORD 기록
ord-9e9b4f013e6e41fe8d4ab299c0212c3e
출처 데이터셋
uspto-grants-1986_09
특허 번호
US04613360

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