Sarcosine → 1-Methyl-3-n-nonyl hydantoin
반응식
Cl[NH:2][C:3]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12]C)=O.N(CC(O)=O)[CH3:15].[OH-].[Na+].[NH:22]1[CH2:28][C:26](=[O:27])N[C:23]1=[O:24]>C(O)(C)(C)C.O>[CH3:15][N:22]1[CH2:28][C:26](=[O:27])[N:2]([CH2:3][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])[C:23]1=[O:24]참가 물질
7
실험 절차
In accordance with the procedure described in Example 6, 41 g (0.2 mol) capric N-chloramide were reacted with sarcosine, sodium hydroxide in a mixture of tertiary butanol and water and then processed. The hydantoin remained in the aqueous solution was an oil, that was extracted with ether. The ether was removed by distillation to yield 43 g (90% yield) 1-methyl-3-n-nonyl hydantoin of the formula ##STR10## having the following analysis:
후처리
- extractionwas extracted with ether
- customThe ether was removed by distillation
출처 및 근거
- ORD 기록
- ord-37b99b25d34c4e0887d8172c6d4f7e0f
- 출처 데이터셋
- uspto-grants-1982_08
- 특허 번호
- US04346233
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