Octane → Styrene

HRID 709344

반응식

HRID 709344 반응식
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.N(C(C)(C)C#N)=N[C:11](C)(C)[C:12]#N.[CH3:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28]>O>[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH:22]([C:23]1[CH:28]=[CH:27][C:26]([CH:11]=[CH2:12])=[CH:25][CH:24]=1)=[CH2:21]

참가 물질

6

반응물 3

HCID 356OctaneHCID 6547AzobisisobutyronitrileHCID 7501Styrene2회

생성물 2

HCID 7501StyreneHCID 66041p-Divinylbenzene

시약·촉매·용매 1

HCID 962Water용매

실험 절차

1 g of the amphiphilic macromolecule reversible addition-fragmentation chain transfer agent and 80 g of deionized water were formulated into an aqueous solution as an aqueous phase, which was added and uniformly mixed with an oil phase consisting of 6 g of styrene, 12 g of p-vinyl benzene, 0.1 g of azobisisobutyronitrile and 9 g of n-octane, and prepared by an ultrasonic crasher into a miniemulsion under the effect of a high shear field. The miniemulsion was transferred to a reactor and subjected to the reaction at a temperature of 80° C. which stopped after 4 hours, and then cooled to the room temperature and discharged to yield polymeric nanocapsules with highly crosslinked shells which were formed by the polymerization of styrene and p-divinyl benzene, wherein the polymeric nanocapsules have an average diameter of 90 nm.

후처리

  1. additionwas added
  2. additionuniformly mixed with an oil phase
  3. customprepared by an ultrasonic crasher into a miniemulsion under the effect of a high shear field
  4. customThe miniemulsion was transferred to a reactor
  5. customsubjected to the reaction at a temperature of 80° C. which
  6. customto yield polymeric nanocapsules with highly crosslinked shells which

출처 및 근거

ORD 기록
ord-2e2acda0e6dc42248c0d402693e5079b
출처 데이터셋
uspto-grants-2015_11
특허 번호
US09180486B2

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