Bis(2-ethylhexyl) phosphate → Potassium bis(2-ethylhexyl) phosphate

HRID 747828

반응식

HRID 747828 반응식
[K].[P:2]([OH:22])([O:13][CH2:14][CH:15]([CH2:20][CH3:21])[CH2:16][CH2:17][CH2:18][CH3:19])([O:4][CH2:5][CH:6]([CH2:11][CH3:12])[CH2:7][CH2:8][CH2:9][CH3:10])=[O:3].[H-].[K+:24].[OH-].[K+]>CCCCCCC>[CH2:11]([CH:6]([CH2:7][CH2:8][CH2:9][CH3:10])[CH2:5][O:4][P:2]([O-:22])([O:13][CH2:14][CH:15]([CH2:20][CH3:21])[CH2:16][CH2:17][CH2:18][CH3:19])=[O:3])[CH3:12].[K+:24]

참가 물질

6

반응물 4

HCID 9275Bis(2-ethylhexyl) phosphate2회HCID 14797Potassium Hydroxide2회HCID 82127Potassium hydrideHCID 5462222Potassium

생성물 1

HCID 23675922Potassium bis(2-ethylhexyl) phosphate

시약·촉매·용매 1

HCID 8900Heptane용매2회

실험 절차

The potassium salt of bis(2-ethylhexyl) hydrogen phosphate was made by the direct reaction of potassium hydride with the corresponding acid in heptane. The acid bis(2-ethylhexyl) hydrogen phosphate (Aldrich Chemicals; 64.49 grams or 0.2 moles) was placed in 300 ml of dry heptane and stirred gently. An excess of potassium hydroxide granules was added to the solution and left to stir until no further potassium hydroxide reacted. At completion the reaction solution was decanted and the heptane evaporated to leave the potassium bis(2-ethylhexyl) phosphate salt as a white waxy solid.

후처리

  1. waitleft
  2. customreacted
  3. customAt completion the reaction solution was decanted
  4. customthe heptane evaporated

출처 및 근거

ORD 기록
ord-b4bd8634624845dba2efd597a5be4759
출처 데이터셋
uspto-grants-2008_07
특허 번호
US07399731B2

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