Dibenzoylmethane → Ethyl Acetoacetate

HRID 861671

반응식

HRID 861671 반응식
C(C1CCCCC1=O)(=O)C.C(C1CCCC1=O)(=O)C.[CH2:20]([O:22][C:23]([CH:25]1CC[CH2:27][C:26]1=[O:30])=[O:24])[CH3:21].C(CC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.CCOC(C1C(=O)CC(C)CC1)=O>>[C:23]([O:22][CH2:20][CH3:21])(=[O:24])[CH2:25][C:26]([CH3:27])=[O:30]

참가 물질

6

반응물 5

HCID 8433DibenzoylmethaneHCID 134002-AcetylcyclohexanoneHCID 69136Ethyl 2-oxocyclopentanecarboxylateHCID 98162Ethyl 4-methyl-2-oxocyclohexanecarboxylateHCID 984712-Acetylcyclopentanone

생성물 1

HCID 8868Ethyl Acetoacetate

실험 절차

Using the same apparatus and procedure as described in Example 1, the onset temperature for a one gram sample of 82.5% di-2-ethylhexyl peroxydicarbonate diluted in OMS was measured. The procedure was repeated with separate samples of the above solution to which ethyl-2-cyclohexanone carboxylate, 2-acetyl cyclohexanone, 2-acetyl cyclopentanone, methyl-2-cycloheptanone carboxylate, ethyl-2-oxocyclopentane carboxylate, dibenzoyl methane, and ethyl-4-methyl-2-cyclohexanone-1-carboxylate had been added. The results are shown in Table II. Results obtained with ethyl acetoacetate, which is disclosed in the prior art, are included for comparison.

후처리

  1. additionhad been added
  2. customResults

출처 및 근거

ORD 기록
ord-71507d96d87d401a998478b7395a67e2
출처 데이터셋
uspto-grants-1998_02
특허 번호
US05714626

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