Dibenzoylmethane → Ethyl Acetoacetate

반응식

C(C1CCCCC1=O)(=O)C.C(C1CCCC1=O)(=O)C.[CH2:20]([O:22][C:23]([CH:25]1CC[CH2:27][C:26]1=[O:30])=[O:24])[CH3:21].C(CC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.CCOC(C1C(=O)CC(C)CC1)=O>>[C:23]([O:22][CH2:20][CH3:21])(=[O:24])[CH2:25][C:26]([CH3:27])=[O:30]

참가 물질

반응물 5

HCID 8433Dibenzoylmethane

HCID 134002-Acetylcyclohexanone

HCID 69136Ethyl 2-oxocyclopentanecarboxylate

HCID 98162Ethyl 4-methyl-2-oxocyclohexanecarboxylate

HCID 984712-Acetylcyclopentanone

생성물 1

HCID 8868Ethyl Acetoacetate

실험 절차

Using the same apparatus and procedure as described in Example 1, the onset temperature for a one gram sample of 82.5% di-2-ethylhexyl peroxydicarbonate diluted in OMS was measured. The procedure was repeated with separate samples of the above solution to which ethyl-2-cyclohexanone carboxylate, 2-acetyl cyclohexanone, 2-acetyl cyclopentanone, methyl-2-cycloheptanone carboxylate, ethyl-2-oxocyclopentane carboxylate, dibenzoyl methane, and ethyl-4-methyl-2-cyclohexanone-1-carboxylate had been added. The results are shown in Table II. Results obtained with ethyl acetoacetate, which is disclosed in the prior art, are included for comparison.