Azobisisobutyronitrile → HCID 86619238, compound

HRID 1010510Notes

Reaction equation

[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].[C:6]([O:11][CH2:12][C:13]([F:21])([F:20])[CH:14]([F:19])[C:15]([F:18])([F:17])[F:16])(=[O:10])[C:7]([CH3:9])=[CH2:8].[C:22]([O:26]CCCC)(=[O:25])[CH:23]=[CH2:24].[CH2:31]=[CH:32][C:33]1[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=1.N(C(C)(C)C#N)=NC(C)(C)C#N.C(OC(C)COC)(=O)C>>[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].[C:6]([O:11][CH2:12][C:13]([F:20])([F:21])[CH:14]([F:19])[C:15]([F:17])([F:18])[F:16])(=[O:10])[C:7]([CH3:9])=[CH2:8].[C:22]([O:26][C:33]([CH3:32])([CH3:34])[CH3:38])(=[O:25])[CH:23]=[CH2:24].[CH2:31]=[CH:32][C:33]1[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=1

Participants

Reactant 6

HCID 6547Azobisisobutyronitrile

HCID 6581Acrylic Acid

HCID 7501Styrene

HCID 7946Propylene glycol methyl ether acetate

HCID 8846Butyl Acrylate

HCID 5497721H,1H,3H-Perfluorobutyl 2-methylacrylate

Product 1

HCID 86619238HCID 86619238, compoundYield 82%

Procedure

Acrylic acid (4.2 g), 2,2,3,4,4,4-hexafluorobutyl methacrylate (14 g), t -butyl acrylate (14 g) and styrene (8.26 g) were mixed with azobisisobutyronitrile (AIBN) (4 g) as a polymerization initiator and propyleneglycol methyl ether acetate (PGMEA) (145 g) as a polymerization solvent. The resulting mixture was reacted at approximately 67° C. for approximately 12 hours, and precipitated in normal hexane and dehydrated to obtain an organic polymer compound with yield of approximately 82% (see FIG. 3).

Workup

customThe resulting mixture was reacted at approximately 67° C. for approximately 12 hours
customprecipitated in normal hexane
customto obtain an organic polymer compound with yield of approximately 82% (see FIG. 3)

Sources & evidence

ORD record: ord-80be31d6cfef40cebd367bf4287b09b7
Source dataset: uspto-grants-2011_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07977035B2

Reaction notes

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