反应详情

40 parts of 9,9-dibutyl-2-iodofluorene, 3.7 parts of aniline, 30 parts of potassium carbonate, 6 parts of copper powders (200 meshes), and 0.87 parts of 18-crown-6 were dissolved in 50 parts of dimethylformamide (DMF), and the obtained solution was reacted in a nitrogen atmosphere at 160° C. for 24 hours. After completion of the reaction, the reaction product was filtrated, and the filtrate was then extracted with ethyl acetate-water. The ethyl acetate phase was dried over magnesium sulfate, and the ethyl acetate was then distilled away, thereby obtaining a brown tarry substance. This brown tarry substance was separated and purified by column chromatography (hexane-ethyl acetate) to obtain 15 parts of 9,9-dibutyl-N-(9,9-dibutylfluorenyl)-N-phenylfluorenamine (the following Compound (344)) in the form of a colorless crystal.

1. customthe obtained solution was reacted in a nitrogen atmosphere at 160° C. for 24 hours
2. customAfter completion of the reaction
3. filtrationthe reaction product was filtrated
4. extractionthe filtrate was then extracted with ethyl acetate-water
5. dry with materialThe ethyl acetate phase was dried over magnesium sulfate
6. distillationthe ethyl acetate was then distilled away
7. customobtaining a brown tarry substance
8. customThis brown tarry substance was separated
9. custompurified by column chromatography (hexane-ethyl acetate)