Glycolaldehyde → HCID 10040359, compound

HRID 1032805Notes

Reaction equation

HRID 1032805 reaction equation
[CH:1](=[O:4])[CH2:2][OH:3].[C:5]([Si:9]([C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1)([C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)Cl)([CH3:8])([CH3:7])[CH3:6].N1C=CN=C1>CN(C)C=O>[Si:9]([O:4][CH2:1][CH:2]=[O:3])([C:5]([CH3:8])([CH3:7])[CH3:6])([C:17]1[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=1)[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1

Participants

5

Reactant 3

HCID 756GlycolaldehydeHCID 795ImidazoleHCID 94078tert-Butyldiphenylchlorosilane

Product 1

HCID 10040359HCID 10040359, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

In the manner described in Example 14c, 5.15 g of glycolaldehyde and 26.78 ml of tert-butyldiphenylchlorosilane were reacted in the presence of 7.61 g of imidazole and 26 ml of absolute dimethylformamide whereby after column chromatography with ether/petroleum ether (1:2) 21.26 g of the title compound were obtained.

Sources & evidence

ORD record
ord-0a8968fd164c437188ac0cf1d4af3f41
Source dataset
uspto-grants-1990_09
Patent number
US04959391

Reaction notes

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