Benzene → [2-(3-Methanesulfonylphenyl)ethynyl]trimethylsilane

HRID 103411Notes

Reaction equation

[Br:1][c:2]1[cH:3][c:4]([S:8](=[O:9])(=[O:10])[CH3:11])[cH:5][cH:6][cH:7]1.[C:19](#[CH:20])[Si:21]([CH3:22])([CH3:23])[CH3:24].[CH3:12][CH2:13][N:14]([CH2:15][CH3:16])[CH2:17][CH3:18].[Cu:31][I:32].[cH:25]1[cH:26][cH:27][cH:28][cH:29][cH:30]1>>[c:2]1([C:20]#[C:19][Si:21]([CH3:22])([CH3:23])[CH3:24])[cH:3][c:4]([S:8](=[O:9])(=[O:10])[CH3:11])[cH:5][cH:6][cH:7]1

Participants

Reactant 5

HCID 241Benzene

HCID 8471Triethylamine

HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

HCID 66111Trimethylsilylacetylene

HCID 2757146Benzene, 1-bromo-3-(methylsulfonyl)-

Product 1

HCID 59240077[2-(3-Methanesulfonylphenyl)ethynyl]trimethylsilane

Sources & evidence

ORD record: ord-c7bd29a155b9472b88c20c99935881c3
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (2/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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