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HRID1042489

反应详情

EQUATION

反应方程式

HRID 1042489 的结构方程式

REACTANTS

反应物

2
结构：COC(=O)C=P(c1ccccc1)(c1ccccc1)c1ccccc1
HCID17453

Methyl (triphenylphosphoranylidene)acetate

C21H19O2P

结构：CCCCOc1cc(C(F)(F)F)ccc1C=O
HCID86649968

未命名化合物

PRODUCTS

生成物

1
结构：CCCCOc1cc(C(F)(F)F)ccc1C=CC(=O)OC
HCID66855719

未命名化合物

收率 90%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCOC(C)=O
溶剂HCID8857

Ethyl acetate

C4H8O2

PROCEDURE

实验过程

2-Butoxy-4-trifluoromethyl-benzaldehyde (420 mg) was reacted with methyl (triphenylphosphoranylidene)acetate (679 mg) at 110° C. overnight as described above to yield title compound (464 mg) after column chromatography (Hex/EtOAc=20/1).