Acetate → Methyl 3-[4-(cyclopropanecarbonyl)phenyl]prop-2-enoate

HRID 106571Notes

Reaction equation

HRID 106571 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([C:8](=[O:9])[CH:10]2[CH2:11][CH2:12]2)[cH:6][cH:7]1.[C:32]([CH:33]=[CH2:34])(=[O:35])[O:36][CH3:37].[C:45]([O-:46])(=[O:47])[CH3:48].[C:50]([O-:51])(=[O:52])[CH3:53].[CH3:38][CH2:39][N:40]([CH2:41][CH3:42])[CH2:43][CH3:44].[Pd+2:49].[c:13]1([P:14]([c:15]2[cH:16][cH:17][cH:18][cH:19][cH:20]2)[c:21]2[cH:22][cH:23][cH:24][cH:25][cH:26]2)[cH:27][cH:28][cH:29][cH:30][cH:31]1>>[c:2]1([CH:34]=[CH:33][C:32](=[O:35])[O:36][CH3:37])[cH:3][cH:4][c:5]([C:8](=[O:9])[CH:10]2[CH2:11][CH2:12]2)[cH:6][cH:7]1

Participants

7

Reactant 6

HCID 175Acetate2×HCID 7294Methyl AcrylateHCID 8471TriethylamineHCID 11776TriphenylphosphineHCID 813944-Bromophenyl cyclopropyl ketoneHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

Product 1

HCID 1474744Methyl 3-[4-(cyclopropanecarbonyl)phenyl]prop-2-enoate

Sources & evidence

ORD record
ord-5bae23dfa6924dba9c246e269a2e0870
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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