Azobisisobutyronitrile → Styrene

HRID 1080884Notes

Reaction equation

HRID 1080884 reaction equation
[Cl:1][CH2:2][C:3]1[CH:10]=[CH:9][C:6]([CH:7]=[CH2:8])=[CH:5][CH:4]=1.[CH2:11]=[CH:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1.N(C(C)(C)C#N)=NC(C)(C)C#N>>[Cl:1][CH2:2][CH:11]=[CH:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1.[CH2:8]=[CH:7][C:6]1[CH:9]=[CH:10][CH:3]=[CH:4][CH:5]=1

Participants

5

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 7501StyreneHCID 74126p-Vinylbenzyl chloride

Product 2

HCID 7501StyreneHCID 94242Benzene, (3-chloro-1-propenyl)-

Procedure

According to the same manner as described in Example 6, p-chloromethylstyrene (82.5 g, 0.541 mole) and styrene (18.8 g, 0.181 mole) were polymerized by using azobis-iso-butyronitrile (1 g) to obtain a copolymer of chloromethylstyrene and styrene as white powder, yield 80%. The structure was confirmed by IR and NMR spectra.

Workup

  1. customwere polymerized

Sources & evidence

ORD record
ord-d612a1c3ebc547669627f40c80f1d5f2
Source dataset
uspto-grants-1996_12
Patent number
US05583230

Reaction notes

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