Triethylamine → HCID 12318732, compound

HRID 1081472Notes

Reaction equation

HRID 1081472 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[C:4]([N+:11]([O-])=O)[CH:3]=1.N[N:15]1[CH2:20][CH2:19][O:18][CH2:17][CH2:16]1.C(N(CC)CC)C>CCO>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[C:4]([NH:11][N:15]2[CH2:20][CH2:19][O:18][CH2:17][CH2:16]2)[CH:3]=1

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 20315N-AminomorpholineHCID 330974-Chloro-1,2-dinitrobenzene

Product 1

HCID 12318732HCID 12318732, compoundYield 52.8%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A mixture of 45 g of 4-chloro-1,2-dinitrobenzene, 25 g of 4-aminomorpholine and 30 g of triethylamine in 250 ml of 96° EtOH is stirred for 48 hours at RT. The precipitate formed is filtered off and washed with iso ether to give 30.2 g of the expected product. M.p.=155° C.

Workup

  1. customThe precipitate formed
  2. filtrationis filtered off
  3. washwashed with iso ether

Sources & evidence

ORD record
ord-b7e1c26a2e2144048e08dae99710f779
Source dataset
uspto-grants-1996_12
Patent number
US05585394

Reaction notes

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