HRID108287

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID6422

Trifluoroacetic acid

C2HF3O2

2 次

HCID8028

Tetrahydrofuran

C4H8O

HCID24350

Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

CuI

HCID58110014

未命名化合物

HCID178461628

未命名化合物

PRODUCTS

产物

HCID58110042

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD记录: ord-d5bbafac1a4c4907b55c3b8e6948ed56
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (2/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (2/10)

反应SMILES

[Br-:1].[CH2:2]([CH3:3])[Mg+:4].[CH2:52]1[O:53][CH2:54][CH2:55][CH2:56]1.[Cl:12][c:13]1[n:14][cH:15][n:16](-[c:18]2[c:19]([O:43][CH3:44])[cH:20][c:21]([NH:24][c:25]3[n:26][n:27]4[c:28]([n:42]3)[CH:29]([c:35]3[cH:36][cH:37][c:38]([F:41])[cH:39][cH:40]3)[CH2:30][C:31](=[O:34])[CH2:32][CH2:33]4)[cH:22][cH:23]2)[cH:17]1.[Cu:57][I:58].[F:45][C:46]([F:47])([F:48])[C:49]([OH:50])=[O:51].[F:5][C:6]([F:7])([F:8])[C:9]([OH:10])=[O:11]>>[CH2:2]([CH3:3])[C:31]1([OH:34])[CH2:30][CH:29]([c:35]2[cH:36][cH:37][c:38]([F:41])[cH:39][cH:40]2)[c:28]2[n:27]([n:26][c:25]([NH:24][c:21]3[cH:20][c:19]([O:43][CH3:44])[c:18](-[n:16]4[cH:15][n:14][c:13]([Cl:12])[cH:17]4)[cH:23][cH:22]3)[n:42]2)[CH2:33][CH2:32]1