Isopropanol → HCID 15702299, compound

HRID 1084678Notes

Reaction equation

HRID 1084678 reaction equation
[OH:1][CH2:2][C:3]1[CH:21]=[CH:20][CH:19]=[CH:18][C:4]=1[C:5]([NH:7][NH:8][C:9]1[CH:14]=[CH:13][C:12]([N+:15]([O-])=O)=[CH:11][CH:10]=1)=[O:6].C(O)(C)C.[Cl-].[NH4+]>[Fe].O>[OH:1][CH2:2][C:3]1[CH:21]=[CH:20][CH:19]=[CH:18][C:4]=1[C:5]([NH:7][NH:8][C:9]1[CH:14]=[CH:13][C:12]([NH2:15])=[CH:11][CH:10]=1)=[O:6]

Participants

6

Reactant 3

HCID 3776IsopropanolHCID 25517Ammonium ChlorideHCID 15702298HCID 15702298, compound

Product 1

HCID 15702299HCID 15702299, compound

Reagents, catalysts & solvents 2

HCID 23925IronCatalystHCID 962WaterSolvent

Procedure

Thereafter, the nitro compound was added to 300 ml of isopropyl alcohol with the addition of 30 ml of water and 3 g of ammonium chloride followed by reflux for 2 hours with the addition of 30 g of reducing iron and then the reflux liquid was filtered and the solid precipitated upon cooling the filtrate was filtered to obtain 4.2 g of 1-(2'-hydroxymethylbenzoyl)-2-(p-aminophenyl)hydrazine.

Workup

  1. filtrationthe reflux liquid was filtered
  2. customthe solid precipitated
  3. temperatureupon cooling the filtrate
  4. filtrationwas filtered

Sources & evidence

ORD record
ord-b11310d77cb448e192283f01a547e2e3
Source dataset
uspto-grants-1991_04
Patent number
US05006445

Reaction notes

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