Chlorosuccinimide → HCID 20062389, compound

HRID 1084791Notes

Reaction equation

HRID 1084791 reaction equation
[Cl:1][C:2]1[CH:10]=[CH:9][C:5]([CH:6]=[N:7][OH:8])=[CH:4][CH:3]=1.ClN1C(=O)CCC1=O.[CH:19]([P:21](=[O:28])([O:25][CH2:26][CH3:27])[O:22][CH2:23][CH3:24])=[CH2:20]>C(N(CC)CC)C>[Cl:1][C:2]1[CH:10]=[CH:9][C:5]([C:6]2[CH2:20][CH:19]([P:21](=[O:28])([O:25][CH2:26][CH3:27])[O:22][CH2:23][CH3:24])[O:8][N:7]=2)=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 31398ChlorosuccinimideHCID 69629Diethyl vinylphosphonateHCID 2191584-Chloro-benzaldehyde oxime

Product 1

HCID 20062389HCID 20062389, compoundYield 102.8%

Reagents, catalysts & solvents 1

HCID 8471TriethylamineSolvent

Procedure

The compound is prepared in analogy to Example 1 from 23.34 g (0.15 mol) of 4-chlorobenzaldoxime, 22 g of N-chlorosuccinimide, 27.1 g of diethyl vinylphosphonate and 22.9 ml of triethylamine, resulting in 49 g of oily product.

Sources & evidence

ORD record
ord-9d7780b8adc445269464f56b9b3bd97e
Source dataset
uspto-grants-1991_04
Patent number
US05006515

Reaction notes

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