tert-Butylcyclohexane → HCID 86744722, compound

HRID 1084945Notes

Reaction equation

HRID 1084945 reaction equation
[C:1]([CH:5]1[CH2:10][CH2:9][CH2:8][CH:7]2[O:11][CH:6]12)([CH3:4])([CH3:3])[CH3:2].C(OC1(O)CCC(C(C)(C)C)CC1)(=O)C(C)=C.C(C1CCCCC1)(C)(C)C.ClC1C=C(C=CC=1)C(OO)=O>C(OC(=O)C)C>[C:1]([CH:5]1[CH2:10][CH2:9][CH:8]=[C:7]2[O:11][CH:6]12)([CH3:4])([CH3:2])[CH3:3]

Participants

6

Reactant 4

HCID 18508tert-ButylcyclohexaneHCID 70297m-Chloroperbenzoic acidHCID 19736151HCID 19736151, compoundHCID 78173523HCID 78173523, compound

Product 1

HCID 86744722HCID 86744722, compound

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

4-t-butyl-2-epoxycyclohexane, an intermediate in the synthesis of 4-t-butylhydroxycyclohexyl methacrylate, is prepared by reacting a 4-t-butylcyclohexane with m-chloroperoxybenzoic acid in ethylacetate below 5° C. until mixing is complete, and then at room temperature for two hours. The reaction mixture is washed with aqueous NA2CO3, dried over MgSO4, and filtered. The theoretical reaction is: ##STR20##

Workup

  1. customis prepared
  2. additionuntil mixing
  3. washThe reaction mixture is washed with aqueous NA2CO3
  4. dry with materialdried over MgSO4
  5. filtrationfiltered
  6. customThe theoretical reaction

Sources & evidence

ORD record
ord-4805c9e53752406f9346b5d54f261c8d
Source dataset
uspto-grants-1991_04
Patent number
US05006622

Reaction notes

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