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HRID1089876

反应详情

EQUATION

反应方程式

HRID 1089876 的结构方程式

REACTANTS

反应物

3
结构：O=C([O-])[O-].[K+].[K+]
HCID11430

Potassium Carbonate

CK2O3

结构：O=C(O)c1n[nH]c2ccccc12
HCID78250

Indazole-3-carboxylic acid

C8H6N2O2

结构：COc1cccc(Br)c1C(=O)O
HCID11117881

2-BROMO-6-METHOXYBENZOIC ACID

C8H7BrO3

PRODUCTS

生成物

1
结构：COc1cccc(-n2nc(C(=O)O)c3ccccc32)c1C(=O)O
HCID19978631

未命名化合物

收率 36.5%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：[O]=[Cu]
催化剂HCID14829

未命名化合物

PROCEDURE

实验过程

3-Indazolecarboxylic acid (1.16 g), 0.81 g of 2-bromo-6-methoxybenzoic acid [described in Chem. Ber., 107, 3874 (1974)], 0.79 g of potassium carbonate and 0.04 g of copper(II) oxide were subjected to reaction in the same manner as in Example 1 to obtain 0.40 g (25.6%) of 1-(2-carboxy-3-methoxyphenyl)-3-indazolecarboxylic acid.