Methacrylic Acid → HCID 86618174, compound

HRID 1093899Notes

Reaction equation

HRID 1093899 reaction equation
[C:1]([O:5][C:6](=[O:9])[CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].[C:10]([OH:15])(=[O:14])[C:11]([CH3:13])=[CH2:12].[C:16]([O:21][CH3:22])(=[O:20])[C:17]([CH3:19])=[CH2:18].N(C(C)(C)C#N)=NC(C)(C)C#N>CC(C)=O>[C:1]([O:5][C:6](=[O:9])[CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].[C:10]([OH:15])(=[O:14])[C:11]([CH3:13])=[CH2:12].[C:16]([O:21][CH3:22])(=[O:20])[C:17]([CH3:19])=[CH2:18]

Participants

6

Reactant 4

HCID 4093Methacrylic AcidHCID 6547AzobisisobutyronitrileHCID 6658Methyl MethacrylateHCID 15458tert-Butyl acrylate

Product 1

HCID 86618174HCID 86618174, compoundYield 88%

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

To acetone (50 g) were dissolved t-butylacrylate (5.0 g), methacrylic acid (2.0 g), methyl methacrylate (3.0 g) and AIBN (2,2′-azobisisobutyronitrile) (0.02 g) as a polymerization initiator, and then the resulting mixture was polymerized at about 67° C. for about 6 hours. After polymerization is completed, the resulting mixture was filtered and vacuum dried to obtain poly(t-butylacrylate/methacrylic acid/methyl methacrylate) (yield: 88%).

Workup

  1. customthe resulting mixture was polymerized at about 67° C. for about 6 hours
  2. customAfter polymerization
  3. filtrationthe resulting mixture was filtered
  4. customvacuum dried

Sources & evidence

ORD record
ord-ce37410fa5bc433d8e54364e4d20b495
Source dataset
uspto-grants-2012_03
Patent number
US08133547B2

Reaction notes

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